hmm, i not sure i come back later with the answer.
I think the correct answer from the choices listed above is option A. The fact that we know about the relationship between the hotter water and the cooler water would be that the <span> hotter water is less dense. Hope this answers the question. Have a nice day.</span>
Answer:
The heat needed to warm 25.3 g of copper from 22°C to 39°C is 165.59 Joules.
Explanation:

Where:
Q = heat absorbed or heat lost
c = specific heat of substance
m = Mass of the substance
ΔT = change in temperature of the substance
We have mass of copper = m = 25.3 g
Specific heat of copper = c = 0.385 J/g°C
ΔT = 39°C - 22°C = 17°C
Heat absorbed by the copper :

The heat needed to warm 25.3 g of copper from 22°C to 39°C is 165.59 Joules.
Answer:
The pH of the buffer solution = 8.05
Explanation:
Using the Henderson - Hasselbalch equation;
pH = pKa₂ + log ( [HPO₄²-]/[H₂PO4⁻]
where pKa₂ = -log (Ka₂) = -log ( 6.1 * 10⁻⁸) = 7.21
Concentration of OH⁻ added = 0.069 M (i.e. 0.069 mol/L)
[H₂PO4⁻] after addition of OH⁻ = 0.165 - 0.069 = 0.096 M
[HPO₄²-] after addition of OH⁻ = 0.594 + 0.069 = 0.663 M
Therefore,
pH = 7.21 + log (0.663 / 0.096)
pH = 7.21 + 0.84
pH = 8.05