Explanation:
Step by step solution by experts to help you in doubt clearance & scoring excellent marks in exams. pH+pOH=14⇒pH=14-3=
Answer:
The solution is not ideal.
The relative strengths of the solute-solvent interactions are greater compared to the solute-solute and solvent-solvent interactions
Explanation:
The total vapor pressure is the sum of the partial pressures of water and methanol, and they are calculated by the Raoult´s law equation:
Pₐ = Xₐ Pºₐ, where Pₐ is the partial pressure of component A
Xₐ is the molar fraction of A
P⁰ₐ is the pressure of pure A
So lets calculate the partial pressures of methanol and water and compare them with the given total vapor pressure of solution:
X H2O = 0.312 ⇒ X CH3OH = 1 - 0.312 = 0.688
PH2O = 0.312 x 55.3 torr = 17.3 torr
PCH3OH = 0.688 x 256 torr = 176.1 torr
Ptotal = PH2O + PCH3OH = 17.3 torr + 176.1 torr = 193.4 torr
This pressure is less than the experimental value of 211 torr. So the solution is not ideal. The relative strength of the solute-solvent interactions are greater than the solute-solute and solvent-solvent interactions.
The reason for this is the presence of hydrogen bonding between methanol and water.
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Answer: The empirical formula is 
Explanation:
Mass of Pb = 4.33 g
Mass of O = (5.00-4.33) g = 0.67 g
Step 1 : convert given masses into moles
Moles of Pb =
Moles of O =
Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.
For Pb = 
For O = 
The ratio of Pb O= 1: 2
Hence the empirical formula is 
Density of liquid=
.
so, density of liquid=
= 1.2 gm/cm³.