A food web has many different links; It links off into different animals. Where as a food chains just a line of single animals that eat those animals for example: like hawks eat bunnies and bunnies eat grass and grass is the producer.
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Starfish have a unique form of digestion in the animal kingdom and a water-vascular system that allows the animal to breathe.
All your answers should be in this article:
http://animals.mom.me/feeding-respiration-starfish-6596.html