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Answer : The fraction of carbonic acid present in the blood is 5.95%
Explanation :
The mixture consists of carbonic acid ( H₂CO₃) and bicarbonate ion ( HCO₃⁻). This represents a mixture of weak acid and its conjugate which is a buffer.
The pH of a buffer is calculated using Henderson equation which is given below.
![pH = pKa + log \frac{[Base]}{[Acid]}](https://tex.z-dn.net/?f=pH%20%3D%20pKa%20%2B%20log%20%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D)
We have been given,
pH = 7.5
pKa of carbonic acid = 6.3
Let us plug in the values in Henderson equation to find the ratio Base/Acid.
![7.5 = 6.3 + log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=7.5%20%3D%206.3%20%2B%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![1.2 = log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=1.2%20%3D%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![\frac{[Base]}{[Acid]} = 10^{1.2}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2010%5E%7B1.2%7D)
![\frac{[Base]}{[Acid]} = 15.8](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2015.8)
![[Base] = 15.8 \times [Acid]](https://tex.z-dn.net/?f=%5BBase%5D%20%3D%2015.8%20%5Ctimes%20%5BAcid%5D)
The total of mole fraction of acid and base is 1. Therefore we have,
![[Acid] + [Base] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%20%5BBase%5D%20%3D%201)
But Base = 15.8 x [Acid]. Let us plug in this value in above equation.
![[Acid] + 15.8 \times [Acid] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%2015.8%20%5Ctimes%20%5BAcid%5D%20%3D%201)
![16.8 [Acid] = 1](https://tex.z-dn.net/?f=16.8%20%5BAcid%5D%20%3D%201)
![[Acid] = \frac{1}{16.8}](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%20%5Cfrac%7B1%7D%7B16.8%7D)
![[Acid] = 0.0595](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%200.0595)
[Acid] = 0.0595 x 100 = 5.95 %
The fraction of carbonic acid present in the blood is 5.95%
Answer:
10 Litre
Explanation:
Given that ::
v1 = 25L ; n1 = 1.5 mole ; v2 =? ; n2 = (1.5-0.9) = 0.6 mole
Using the relation :
(n2 * v1) / n1 = (n2 * v2) / n2
v2 = (n2 * v1) / n1
v2 = (0.6 mole * 25 Litre) / 1.5 mole
v2 = 15 / 1.5 litre
v2 = 10 Litre
Answer:
0.185M sulfuric acid
Explanation:
Based on the reaction:
H₂SO₄ + 2KOH → K₂SO₄ + 2H₂O
<em>1 mole of sulfuric acid reacts with 2 moles of KOH</em>
Initial moles of H₂SO₄ and KOH are:
H₂SO₄: 0.750L ₓ (0.470mol / L) = <em>0.3525 moles of H₂SO₄</em>
KOH: 0.700L ₓ (0.240mol / L) = <em>0.168 moles of KOH</em>
The moles of sulfuric acis that react with KOH are:
0.168mol KOH ₓ (1 mole H₂SO₄ / 2 moles KOH) = 0.0840 moles of sulfuric acid.
Thus, moles that remain are:
0.3525moles - 0.0840 moles = <em>0.2685 moles of sulfuric acid remains</em>
As total volume is 0.700L + 0.750L = 1.450L, concentration is:
0.2685mol / 1.450L = <em>0.185M sulfuric acid</em>
Hoi!!
its true
hope this help!!
:) np
