Angles 3 and 1 are vertical angles, and angles 2 and 4 are vertical angles. Vertical angles are congruent by definition, so angle 3 is congruent to angle 1, and angle 2 is congruent to angle 4.
The adjacent angles are supplementary (they add to equal 180 degrees) so you can set up an equation to solve for x.
180 = 2x + x 180 = 3x 60 = x
x = 60
To find the measure if each angle, plug in x as needed.