Answer:
Any of the answers given will work
Explanation:
I literally just did it.
Answer:
a) 
b) 
d) 
d) 
Explanation:
From the question we are told that:
Moles of N2 
Atmospheric pressure 
Temperature 

Initial heat 
a)
Generally the equation for change in temperature is mathematically given by

Where




b)
Generally the equation for ideal gas is mathematically given by

For v double


Therefore



Total Work-done 



c)
Generally the equation for amount of heat added is mathematically given by



d)
Generally the equation for change in internal energy of the gas is mathematically given by



Answer :
(1) pH = 1.27
(2) pH = 13.35
(3) The given solution is not a buffer.
Explanation :
<u>(1) 53.1 mM HCl</u>
Concentration of HCl = 
As HCl is a strong acid. So, it dissociates completely to give hydrogen ion and chloride ion.
So, Concentration of hydrogen ion= 
pH : It is defined as the negative logarithm of hydrogen ion concentration.
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)


<u>(2) 0.223 M KOH</u>
Concentration of KOH = 0.223 M
As KOH is a strong base. So, it dissociates completely to give hydroxide ion and potassium ion.
So, Concentration of hydroxide ion= 0.223 M
Now we have to calculate the pOH.
![pOH=-\log [OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%20%5BOH%5E-%5D)


Now we have to calculate the pH.

<u>(3) 53.1 mM HCl + 0.223 M KOH</u>
Buffer : It is defined as a solution that maintain the pH of the solution by adding the small amount of acid or a base.
It is not a buffer because HCl is a strong acid and KOH is a strong base. Both dissociates completely.
As we know that the pH of strong acid and strong base solution is always 7.
So, the given solution is not a buffer.
Answer:
negative
Explanation:
Entropy is a measure of the "disorder" in a system.
In this reaction, the amount of disorder decreases. This is because one gas molecule (NH₃) has more order than two gas molecules (N₂ and H₂). Therefore, the entropy change should be negative.
Answer:
The second one is the answer