When light passes from one medium to another at an angle, it may refract, or bend, according to Snell's law:
n₁sin(θ₁) = n₂sin(θ₂)
n₁ = index of first medium, θ₁ = angle of incidence, n₂ = index of second medium, θ₂ = angle of refraction
Given values:
n₁ = 1.33 (water), θ₁ = 45.0°, θ₂ = 40.3°
Plug in and solve for n₂:
1.33sin(45.0°) = n₂sin(40.3°)
n₂ = 1.454
I looked up this value on the HyperPhysics indices of refraction table... The index we calculated is closest to 1.46, which is that of fused quartz.