Answer:
2.75 × 10⁻⁶ M/s
1.69 × 10⁻⁶ M/s
9.23 × 10⁻⁻⁷ M/s
4.43 × 10⁻⁻⁷ M/s
2.1 × 10⁻⁻⁷ M/s
Explanation:
We have the following information for the isomerization of methyl isonitrile
Time (s) [CH₃NC] (M)
0 0.0165
2000 0.0110
5000 0.00591
8000 0.00314
12000 0.00137
15000 0.00074
To calculate the average rate of reaction (r) for each interval, we need to use the following expression:
r = -Δ[CH₃NC]/Δt
Interval 0-2000 s
r = - (0.0110 M-0.0165 M)/2000 s - 0 s = 2.75 × 10⁻⁶ M/s
Interval 2000-5000 s
r = - (0.00591 M-0.0110 M)/5000 s - 2000 s = 1.69 × 10⁻⁶ M/s
Interval 5000-8000 s
r = - (0.00314 M-0.00591 M)/8000 s - 5000 s = 9.23 × 10⁻⁻⁷ M/s
Interval 8000-12000 s
r = - (0.00137 M - 0.00314 M)/12000 s - 8000 s = 4.43 × 10⁻⁻⁷ M/s
Interval 12000-15000 s
r = - (0.00074 M - 0.00137 M)/15000 s - 12000 s = 2.1 × 10⁻⁻⁷ M/s
Answer:
Explanation:
The number of moles of solute is equal to product of the molar concentration (molarity) and the volume (in liters) of solution.
Since the volumes and the molar concentrations of the<em> NaOH </em>and <em>HCl </em>solutions mixed are equal, each one of them contributes the same number of moles of solute.
Since every mol of NaOH produces one mol of OH⁻ ions and every mol of HCl produces one mol of H⁺ ion, the number of moles of OH ⁻ and H⁺ in solution are equal.
Thus, OH⁻ and H⁺ ions will be neutralized by the reaction:
- OH⁻ (aq) + H⁺ (aq) ⇄ H₂O (l)
Which is strongly shifted to the right and has <em>neutral pH</em>.
Hence, you conclude that the approximate <em>pH of the solution is neutral.</em>
Answer:
1-ethyl-2-methyl cyclopropane.
Explanation:
- The structure of the molecule will be as shown in the attached image.
- The molecular formula of the compound is C₆H₁₂.
- It has 3 membered ring with 3 C atoms and two substituents one of them with one C atom (methyl) and the other with 2 C atoms (ethyl).
- The ring consist of 3 C atoms, so its name is cyclo propane.
- We numbering the atoms of the ring that give the ethyl substituent the low no. (1) and then methyl group take no. (2).
- <em>Thus, the name of the compound is 1-ethyl-2-methyl cyclopropane.</em>
Answer: sodium amide undergoes an acid -base reaction
Explanation:
sodium amide is a ionic compound and basically exists as sodium cation and amide anion. Amide anion is highly basic in nature and hence as soon as there is amide anion generated in the solution , Due to its very pronounced acidity it very quickly abstracts the slightly acidic proton available on methanol.
This leads to formation of ammonia and sodium methoxide.
Hence sodium amide reacts with methanol and abstracts its only acidic proton and form ammonia and sodium Methoxide.
Hence the 3rd statement is a corrects statement.
So we cannot use methanol for sodium amide because sodium amide itself would react with methanol and the inherent molecular natur of sodium amide would then change.
The 1st and 2nd statements both are incorrect because both the compounds methanol as well as sodium amide have dipole moments and hence are polar molecules.
The 4th statement is also incorrect as both the molecules have dipole moment and hence there would be ion-dipole forces operating between them.
The following reaction occurs:
NaNH₂+CH₃OH→NH₃+CH₃ONa