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shepuryov [24]
3 years ago
6

Which of the following statements concerning coordinate covalent bonds is correct? Group of answer choices One of the atoms invo

lved must be a metal and the other a nonmetal. Both atoms involved in the bond contribute three electrons to the bond. Once formed, they are indistinguishable from any other covalent bond. They occur only in molecules where all bonds are single bonds.
Chemistry
1 answer:
lys-0071 [83]3 years ago
6 0
One of the atoms involved must be a metal and the other a nonmetal
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M = 163 m/z) is formed.
DanielleElmas [232]

Answer:

            As the molecular mass of given amine is 163 g/mol (a odd number) it means that this compound contains a odd number of Nitrogen atoms. We will first apply Rule of Thirteen to get the molecular formula.

Rule of Thirteen:

First divide the parent peak value by 13 as,

                = 163 ÷ 13

                = 12.53

Now, multiply 13 by 12,

                = 13 × 12 (here, 12 specifies number of carbon atoms)

                = 156

Now subtract 156 from 163,

                = 163 - 156

                = 7

Add 7 into 12,

                = 7 + 12

                = 19 (hydrogen atoms)

So, the rough formula we have is,

                                                       C₁₂H₁₉

Now, add one Nitrogen atom to above formula and subtract one Carbon and 2 Hydrogen atoms as these numbers are equal to atomic mass of Nitrogen atom as,

                C₁₂H₁₉   -------N-------->    C₁₁H₁₇N

Also, as shown in ¹³C-NMR there is one peak around 180 ppm and the peak at 1661 cm⁻¹ in IR spectrum is characteristic to carbonyl group hence, we will add one oxygen atom to the chemical formula accordingly. i.e.

                C₁₁H₁₇N   -------O-------->    C₁₀H₁₃NO

Molecular Formula: C₁₀H₁₃NO

Also,

In NMR the the four peaks around 120 ppm are assigned to a mono substituted benzene ring.

The absence of IR peak above 3200 cm⁻³ also confirms that the amine is tertiary in nature and there is no hydrogen attached to the nitrogen atom.

It can be observed that the peaks in upfield are duplicating. This can be due to the presence of rotamers of said compound.

The most plausible structure for given data is shown below, and the resonance structure along with rotamers are also shown.

6 0
3 years ago
A gas at a constant volume has an initial temperature of 300.0 K and an initial pressure of 10.0 atm. What pressure does the gas
harkovskaia [24]
\frac{500}{300} times 10=16.667 atm
4 0
3 years ago
Please help!
ANEK [815]

Answer:

A- Physical, B- Chemical, C- chemical, D- Physical

Explanation:

A is physical because you can see it changing its form is changing.

B is Chemical because a new substance is formed creating the orange color of rust.

C is a Chemical reaction because it is being broken down so the banana itself is changing not just how we see it.

D is physical because we are just changing the shape/ size of the item, not anything to do with its substances.

8 0
2 years ago
Read 2 more answers
Fish breathe the dissolved air in water through their gills. Assuming the partial pressures of oxygen and nitrogen in air to be
amid [387]

Answer:

X(O₂) = 0.323

X(N₂) = 0.677

Explanation:

We have the partial pressures of oxygen (O₂) and nitrogen (N₂):

P(O₂) = 0.20 atm

P(N₂) = 0.80 atm

In order to solve the problem, you need the solubilities of each gas in water at 298 K. We can consider 1.3 x 10⁻³ mol/(L atm) for oxygen (O₂) and 6.8 x 10⁻⁴mol/(L atm) for nitrogen (N₂) from the bibliography.

s(O₂) = 1.3 x 10⁻³ mol/(L atm)

s(N₂) = 6.8 x 10⁻⁴mol/(L atm)

So, we calculate the concentration (C) of each gas as the product of its partial pressure (P) and the solubility (s):

C(O₂) = P(O₂) x s(O₂) = 0.20 atm x 1.3 x 10⁻³ mol/(L atm) = 2.6 x 10⁻⁴mol/L

C(N₂) = P(N₂) x s(N₂) = 0.80 atm x 6.8 x 10⁻⁴mol/(L atm) = 5.44 x 10⁻⁴ mol/L

In 1 liter of water, we have the following number of moles (n):

n(O₂) = 2.6 x 10⁻⁴ mol

n(N₂) = 5.44 x 10⁻⁴ mol

Thus, the total number of moles (nt) is calculated as the sum of the number of moles of the gases in the mixture:

nt = n(O₂) + n(N₂) = 2.6 x 10⁻⁴ mol + 5.44 x 10⁻⁴ mol = 8.04 x 10⁻⁴ mol

Finally, the mole fraction of each gas is calculated as the ratio between the number of moles of each gas and the total number of moles:

X(O₂) = n(O₂)/nt = 2.6 x 10⁻⁴ mol/(8.04 x 10⁻⁴ mol) = 0.323

X(N₂) = n(N₂)/nt = 5.44 x 10⁻⁴ mol/(8.04 x 10⁻⁴ mol) = 0.677

5 0
3 years ago
Is ninhydren test positive for protein?
lyudmila [28]
The Ninhydrin test is not effective to detect high molecular weight proteins as the steric hindrance limits the ninhydrin from reaching the α-amino groups.
5 0
2 years ago
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