CH4 has more ideal gas behavior than CCl4 due to its higher intermolecular interaction.
We must note that ideal gases have minimal interaction with each other. Hence, in deciding which gas has ideal gas behavior, we have to consider the gas that has the least degree of intermolecular interaction.
However, the both gases contain nonpolar molecules but CCl4 has a greater molecular mass and has more intermolecular interaction than CH4 hence CH4 has greater ideal gas behavior than CCl4.
