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Answer:
439.7nm
Explanation:
Energy of a quantum can be calculated using below formula
E=hv...........eqn(1)
But v=λ/ c .........eqn(2)
If we substitute eqn(2) into eqn(1) we have
E= hc/(λ)
Where E= energy
h= Plank's constant= 6.62607004 × 10-34 m2 kg / s
c= speed of light
c= 2.998 × 10^8 m/s
λ= wavelength= ?
But the energy was given in Kj , it must be converted to Kj/ photon for unit consistency.
Energy E= 272 kJ/mol × 1mol/6.02× 10^23
Energy= 451.83× 10^-24 Kj/ photon
E= hc/(λ)...........eqn(1)
If we make λ subject of the formula
λ= hc/E
Then substitute the values we have
λ= [(6.626 × 10^-34) × (2.998 × 10^8)]/451.83× 10^-24
λ=(0.00043965) × (1Kj/1000J) × (10^9nm/1m)
λ=439.7nm
Hence, the longest wavelength of radiation with enough energy to break carbon-sulfur bonds is 439.7nm
In a chemical reaction equation.. There must be redox reaction taking palce.. So oxidation and reduction reactions will be happening on both sides of the equation.. You can separate the oxidation and reduction equations in halves. . So there will be one half oxidation equation and the other half reduction equation of the reaction.