Consider the isomerization of butane with equilibrium constant is 2.5 .The system is originally at equilibrium with :
[butane]=1.0 M , [isobutane]=2.5 M
If 0.50 mol/L of butane is added to the original equilibrium mixture and the system shifts to a new equilibrium position, what is the equilibrium concentration of each gas?
Answer:
The equilibrium concentration of each gas:
[Butane] = 1.14 M
[isobutane] = 2.86 M
Explanation:
Butane ⇄ Isobutane
At equilibrium
1.0 M 2.5 M
After addition of 0.50 M of butane:
(1.0 + 0.50) M -
After equilibrium reestablishes:
(1.50-x)M (2.5+x)
The equilibrium expression will wriiten as:
![K_c=\frac{[Isobutane]}{[Butane]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BIsobutane%5D%7D%7B%5BButane%5D%7D)

x = 0.36 M
The equilibrium concentration of each gas:
[Butane]= (1.50-x) = 1.50 M - 0.36M = 1.14 M
[isobutane]= (2.5+x) = 2.50 M + 0.36 M = 2.86 M
Answer:
Volume of ammonia produced = 398.7 dm³
Explanation:
Given data:
Volume of N₂ = 200 dm³
Pressure and temperature = standard
Volume of ammonia produced = ?
Solution:
Chemical equation:
N₂ + 3H₂ → 2NH₃
Number of moles of N₂:
PV = nRT
1 atm× 200 L = n× 0.0821 atm.L/mol.K × 273 K
n = 200 atm.L /22.41 atm.L/mol
n = 8.9 mol
Now we will compare the moles of ammonia and nitrogen.
N₂ : NH₃
1 : 2
8.9 : 2/1×8.9 = 17.8 mol
Volume of ammonia:
1 mole of any gas occupy 22.4 dm³ volume
17.8 mol ×22.4 dm³/1 mol = 398.7 dm³
Just like how heat moves from a region of higher
temperature to a region of lower temperature, molecules also tend to move from
a region of higher concentration to a region of lower concentration. This is
called natural diffusion and is naturally happening to reach stability.
Answer:
<u>STEP I</u>
This is the balanced equation for the given reaction:-

<u>STEP II</u>
The compounds marked with (aq) are soluble ionic compounds. They must be
broken into their respective ions.
see, in the equation KOH, H2SO4, and K2SO4 are marked with (aq).
On breaking them into their respective ions :-
- 2KOH -> 2K+ + 2OH-
- H2SO4 -> 2H+ + (SO4)2-
- K2SO4 -> 2K+ + (SO4)2-
<u>STEP III</u>
Rewriting these in the form of equation

<u>STEP </u><u>IV</u>
Canceling spectator ions, the ions that appear the same on either side of the equation
<em>(note: in the above step the ions in bold have gotten canceled.)</em>

This is the net ionic equation.
____________________________

- KOH has been taken as aqueous because the question informs us that we have a solution of KOH. by solution it means that KOH has been dissolved in water before use.
[Alkali metal hydroxides are the only halides soluble in water ]