The half life of the substance is 8 hours , Option D is the correct answer.
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What is Half Life ?
Half-life is the time required by an unstable element  to reduce to half of its initial value. 
The term is commonly used in nuclear physics.
The formula is 

N(t)     =    quantity of the substance remaining
N ₀      =    initial quantity of the substance
t    =  time elapsed
    =    half life of the substance
The data given in the question is N ₀ = 800 moles , N(t)= 100 , t= 24 hours

Substituting values in the equation 


Therefore half life of the substance is 8 hours , Option D is the correct answer.
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