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Murljashka [212]
3 years ago
9

If the change of enthalpy of this reaction when proceeding left to right is +14 kcal, which chemical equation is correct?

Chemistry
1 answer:
bagirrra123 [75]3 years ago
7 0

Answer:

N₂O₄ + 14 kcal ⇄ 2NO₂.

Explanation:

Since the sign of ΔH determines either the reaction is exothermic or endothermic:

+ve, the reaction is endothermic.

-ve, the reaction is exothermic.

∵ The change of enthalpy of this reaction when proceeding left to right is + 14 kcal (+ ve sign).

∴ The reaction is endothermic, the heat is a part of the reacatnts in the reaction.

So, the reaction is:

N₂O₄ + 14 kcal ⇄ 2NO₂.

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Answer:

The ΔHrxn for the above equation = 179 kJ/mol

Explanation:

The reaction bond enthalpies are for the reactant;

3 × N-H = 3 × 390 = 1,170 kJ/mol

2 × O=O = 2 × 502 = 1004 kJ/mol

The reaction bond enthalpies are for the product;

3 × N-O = 3 × 201 = 603 kJ/mol

3 × O-H = 3 × 464 = 1,392 kJ/mol

The ΔHrxn for the above equation is therefore;

ΔHrxn = 1,170 + 1,004 - (603 + 1,392) = 179 kJ/mol

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3 years ago
0.25 mol of nitric acid is used to make a 0.10 M nitric acid solution. How many grams of solute was used?
Yanka [14]

Answer:

15.75 grams of HNO3 was used and dissolved in 2.5 liters of solvent, to make a 0.10 M solution

Explanation:

Step 1: Data given

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Number of moles nitric acid (HNO3) = 0.25 moles

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Step 2: Calculate molar mass of nitric acid

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Mass HNO3 = moles HNO3 * molar mass HNO3

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