How much of your blood is made of Plasma? A)10% <br> B)25% c)40% d)50%

Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid (HC3H5O2, Ka= 1.3x10-5 ) (b) 0.1000M sodium prop

jek_recluse [69]

(a) The pH of 0.1000 M propanoic acid (HC3H5O2) is 2.9.

(b) The pH of 0.1000 M sodium propanoate (NaC3H5O2) is 8.9.

(c) The pH of 0.1000 M propanoic acid (HC3H5O2) and 0.1000 M sodium propanoate (NaC3H5O2) is 4.9.

<h3>Further explanation:</h3>

(a)

Given information:

The value of acid ionization constant for propanoic acid is 1.3 x $10^{-5}$ .

The initial concentration of propanoic acid is .

To calculate:

The pH of 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid. It ionizes partially in water as follows:

The expression for acid dissociation constant is,

…… (1)

Here,

is ionization constant of propanoic acid.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydronium ion.

is the equilibrium concentration of propanoic acid.

ICE table (1):

Refer ICE table (1),

Substitute the values form the ICE table (1) in equation (1).

The approximation x is very small is valid. Therefore, the value of x can be neglected. Above equation can be modified as,

Rearrange above equation for x.

…… (2)

Substitute for in equation (2) to calculate the value of x.

Therefore, from the ICE table (1) the concentration of hydronium ion is,

.

The negative logarithm of hydronium ion concentration is defined as the pH of the solution. Mathematically,

…… (3)

Substitute for in equation (3) to calculate the pH of the solution.

(b)

Given information:

The value of acid ionization constant for propanoic acid is .

The initial concentration of sodium propanoate is .

To calculate:

The pH of 0.1000 M sodium propanoate solution.

Solution:

Sodium propanoate is conjugate base of weak propanoic acid. It undergoes hydrolysis in water to yield hydroxide ion in the solution as follows:

…… (4)

Propanoic acid is a weak acid. It ionizes partially in water as follows:

…… (5)

Dissociation reaction for water is written as follows:

…… (6)

From equation (4), (5), and (6) the relationship between and is,

…… (7)

Substitute for and for in equation (7).

ICE table (2):

The expression for base dissociation constant is,

…… (8)

Here,

is base ionization constant.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydroxide ion.

is the equilibrium concentration of propanoic acid.

From the ICE table (2),

Substitute the values form the ICE table (2) in equation (8).

The approximation y is very small is valid. Therefore, the value of y can be neglected. Above equation can be modified as,

Rearrange above equation for y.

…… (9)

Substitute for in equation (9) to calculate the value of y.

Therefore, from the ICE table (2) the concentration of hydroxide ion is,

The negative logarithm of hydroxide ion concentration is defined as pOH of the solution. Mathematically,

…… (10)

Substitute for in equation (10) to calculate pOH of the solution.

The relation between pH and pOH is as follows:

…… (11)

Substitute 5.057 for pOH in equation (11) to calculate the pH of the solution.

(c)

Given information:

The value of acid ionization constant for propanoic acid is .

The initial concentration of sodium propanoate is .

To calculate:

The pH of 0.1000 M sodium propanoate and 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid, and sodium propanoate is salt of the conjugate base of propanoic acid. Thus, propanoic acid and sodium propanoate will form a buffer system.

The pH of the buffer solution can be determined with the help of the Henderson-Hasselbalch equation. Mathematically,

For propanoic acid and sodium propanoate buffer system, the Henderson-Hasselbalch equation can be modified as,

…… (12)

The negative logarithm of acid ionization constant is equal to .

…… (13)

Substitute for in equation (13).

Substitute for , for and 4.9 for in equation (12).

Learn more:

1. About Henderson-Hasselbalch equation brainly.com/question/12999557

2. Learn more about how to calculate moles of the base in given volume brainly.com/question/4283309

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Ionic equilibria

Keywords: ionic equilibrium, propanoic acid, sodium propanoate, ionization constant, weak acid, conjugate base, equilibrium concentration, hydronium ion, hydroxide ion, pH, pOH, ICE table, negative logarithm, buffer solution, Henderson-Hasselbalch equation, 0.1000 M, 4.9, 8.9, 2.9.

3 0

3 years ago

Read 2 more answers

1. The elements on the Periodic Table are arranged in order of increasing

s344n2d4d5 [400]

Answer:

Atomic number

Explanation:

8 0

2 years ago

Read 2 more answers

A mixture of 15.0 g of the anesthetic halothane (C2HBrClF3 197.4 g/mol) and 22.6 g of oxygen gas has a total pressure of 862 tor

AlexFokin [52]

Answer : The partial pressure of $C_2HBrClF_3$ and $O_2$ are, 84 torr and 778 torr respectively.

Explanation : Given,

Mass of $C_2HBrClF_3$ = 15.0 g

Mass of $O_2$ = 22.6 g

Molar mass of $C_2HBrClF_3$ = 197.4 g/mole

Molar mass of $O_2$ = 32 g/mole

First we have to calculate the moles of $C_2HBrClF_3$ and $O_2$ .

$\text{Moles of }C_2HBrClF_3=\frac{\text{Mass of }C_2HBrClF_3}{\text{Molar mass of }C_2HBrClF_3}=\frac{15.0g}{197.4g/mole}=0.0759mole$

and,

$\text{Moles of }O_2=\frac{\text{Mass of }O_2}{\text{Molar mass of }O_2}=\frac{22.6g}{32g/mole}=0.706mole$

Now we have to calculate the mole fraction of $C_2HBrClF_3$ and $O_2$ .

$\text{Mole fraction of }C_2HBrClF_3=\frac{\text{Moles of }C_2HBrClF_3}{\text{Moles of }C_2HBrClF_3+\text{Moles of }O_2}=\frac{0.0759}{0.0759+0.706}=0.0971$

and,

$\text{Mole fraction of }O_2=\frac{\text{Moles of }O_2}{\text{Moles of }C_2HBrClF_3+\text{Moles of }O_2}=\frac{0.706}{0.0759+0.706}=0.903$

Now we have to partial pressure of $C_2HBrClF_3$ and $O_2$ .

According to the Raoult's law,

$p^o=X\times p_T$

where,

$p^o$ = partial pressure of gas

$p_T$ = total pressure of gas

$X$ = mole fraction of gas

$p_{C_2HBrClF_3}=X_{C_2HBrClF_3}\times p_T$

$p_{C_2HBrClF_3}=0.0971\times 862torr=84torr$

and,

$p_{O_2}=X_{O_2}\times p_T$

$p_{O_2}=0.903\times 862torr=778torr$

Therefore, the partial pressure of $C_2HBrClF_3$ and $O_2$ are, 84 torr and 778 torr respectively.

6 0

2 years ago

A sample of helium gas occupies a volume of 152.0 mL at a pressure of 717.0 mm Hg and a temperature of 315.0 K. What will the vo

kozerog [31]

Answer:

0.581 L or 581 mL

Explanation:

As stated in the question, the combined gas law is (P1*V1/T1) = (P2*V2/T2)

Write down the amounts you are given.

V1 = 0.152 L (I was taught to always convert milliliters to liters)

P1 = 717 mmHg

T1 = 315 K

V2 = ?

P2 = 463 mmHg

T2 = 777 K

The variable that is being solved for is final volume. Fill in the combined gas law equation with the corresponding amounts and solve for V2.

(717 mmHg*0.152 L) / (315 K) = (463 mmHg*V2) / (777 K)

0.346 = (463*V2) / (777)

0.346*777 = (463*V2) / (777)*777

268.842 = 463*V2

268.842/463 = (463*V2)/463

V2 = 0.581

Pressure and volume are indirectly proportional. This checks out because the volume increased while pressure decreased. Volume and temperature are directly proportional. This checks out because both volume and temperature increased. This is a good way to check your answers. You can also solve each side of the combined gas law equation to see if they are both the same.

6 0

2 years ago

8. What is the name of this compound?

olga2289 [7]

Answer:

tert-butyl bromide

Explanation:

sec-butyl bromide

CH3 -CH-CH2-CH3

Br

tert-butyl bromide

CH3

CH3-C- Br

CH3

isopropyl bromide

CH3

CH3-CH-Br

isobutyl bromide

CH3

CH3-CH-CH2-Br

6 0

3 years ago

How much of your blood is made of Plasma? A)10% B)25% c)40% d)50%