Answer:
The molar solubility of lead bromide at 298K is 0.010 mol/L.
Explanation:
In order to solve this problem, we need to use the Nernst Equaiton:
![E = E^{o} - \frac{0.0591}{n} log\frac{[ox]}{[red]}](https://tex.z-dn.net/?f=E%20%3D%20E%5E%7Bo%7D%20-%20%5Cfrac%7B0.0591%7D%7Bn%7D%20log%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D)
E is the cell potential at a certain instant, E⁰ is the cell potential, n is the number of electrons involved in the redox reaction, [ox] is the concentration of the oxidated specie and [red] is the concentration of the reduced specie.
At equilibrium, E = 0, therefore:
![E^{o} = \frac{0.0591}{n} log \frac{[ox]}{[red]} \\\\log \frac{[ox]}{[red]} = \frac{nE^{o} }{0.0591} \\\\log[red] = log[ox] - \frac{nE^{o} }{0.0591}\\\\[red] = 10^{ log[ox] - \frac{nE^{o} }{0.0591}} \\\\[red] = 10^{ log0.733 - \frac{2x5.45x10^{-2} }{0.0591}}\\\\](https://tex.z-dn.net/?f=E%5E%7Bo%7D%20%20%3D%20%5Cfrac%7B0.0591%7D%7Bn%7D%20log%20%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D%20%5C%5C%5C%5Clog%20%5Cfrac%7B%5Box%5D%7D%7B%5Bred%5D%7D%20%3D%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%20%5C%5C%5C%5Clog%5Bred%5D%20%3D%20%20log%5Box%5D%20-%20%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%5C%5C%5C%5C%5Bred%5D%20%3D%2010%5E%7B%20log%5Box%5D%20-%20%20%5Cfrac%7BnE%5E%7Bo%7D%20%7D%7B0.0591%7D%7D%20%5C%5C%5C%5C%5Bred%5D%20%3D%2010%5E%7B%20log0.733%20-%20%20%5Cfrac%7B2x5.45x10%5E%7B-2%7D%20%20%7D%7B0.0591%7D%7D%5C%5C%5C%5C)
[red] = 0.010 M
The reduction will happen in the anode, therefore, the concentration of the reduced specie is equivalent to the molar solubility of lead bromide.
"The forces of attraction and the volume of the molecules" (as opposed to the volume of the container the gas is in).
Calculate the root mean square velocity of nitrogen molecules at 25°C.
297 m/s
149 m/s
515 m/s
729 m/s
The new pressure is larger than the original, the new volume is smaller than 9.0 ml and the new volume is 6.0
good luck :D