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vladimir2022 [97]
2 years ago
10

A scientist measures the standard enthalpy change for the following reaction to be -139.5 kj :

Chemistry
1 answer:
jeyben [28]2 years ago
7 0

Answer:

A scientist measures the standard enthalpy change for the following reaction to be -139.5 kj :

h2(g) + c2h4(g)c2h6(g)

based on this value and the standard enthalpies of formation for the other substances, the standard enthalpy of formation of c2h4(g) is _____ kj/mol

Explanation:

Hydrogen ΔHof (kJ/mol) ΔGof (kJ/mol) So (J/mol K)

H2 (g)

0

0

130.7

Carbon ΔHof (kJ/mol) ΔGof (kJ/mol) So (J/mol K)

C2H6 (g)

-84.7

-32.8

229.6

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The system co2(g) + h2(g) ⇀↽ h2o(g) + co(g) is at equilibrium at some temperature. at equilibrium a 4.00 l vessel contains 1.00
Marina CMI [18]

<u>Answer:</u> The moles of CO_2 added to the system is 7.13 moles

<u>Explanation:</u>

We are given:

Moles of CO_2 at equilibrium = 1.00 moles

Moles of H_2 at equilibrium = 1.00 moles

Moles of H_2O at equilibrium = 2.40 moles

Moles of CO at equilibrium = 2.40 moles

Volume of the container = 4.00 L

Concentration is written as:

\text{Molarity}=\frac{\text{Moles}}{\text{Volume (in L)}}

The given chemical equation follows:

CO_2(g)+H_2(g)\rightleftharpoons H_2O(g)+CO(g)

The expression of K_c for above equation follows:

K_c=\frac{[CO][H_2O]}{[CO_2][H_2]}

Putting values in above equation, we get:

K_c=\frac{(\frac{2.40}{4.00})\times (\frac{2.40}{4.00})}{(\frac{1.00}{4.00})\times (\frac{1.00}{4.00})}\\\\K_c=5.76

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}

Molarity of CO = 0.791 mol/L

Volume of solution = 4.00 L

Putting values in above equation, we get:

0.791M=\frac{\text{Moles of CO}}{4.00L}\\\\\text{Moles of CO}=(0.791mol/\times 4.00L)=3.164mol

Extra moles of CO = (3.164 - 2.40) = 0.764 moles

Let the moles of CO_2 needed be 'x' moles.

Now, equilibrium gets re-established:

              CO_2(g)+H_2(g)\rightleftharpoons H_2O(g)+CO(g)

Initial:       1.00      1.00              2.40       2.40

At eqllm:   (0.236+x)   0.236      3.164     3.164

Again, putting the values in the expression of K_c, we get:

5.76=\frac{(\frac{3.164}{4.00})\times (\frac{3.164}{4.00})}{(\frac{0.236+x}{4.00})\times (\frac{0.236}{4.00})}\\\\5.76=\frac{10.011}{0.056+0.236x}\\\\x=7.13

Hence, the moles of CO_2 added to the system is 7.13 moles

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This question comes with four answer choices:

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