When a system is in dynamic equilibrium, the forward reaction rate and the backward reaction rate are equal or occurs at the same rate. Therefore, the third option above is the most accurate one. Hope this answers the question. Have a nice day.
Answer:
of water at 30C and 1 atm is 256.834 J/mol·K.
Explanation:
To solve the question, we note the Maxwell relation such as

Where:
= Specific heat of gas at constant pressure = 75.3 J/mol·K
= Specific heat of gas at constant volume = Required
T = Temperature = 30 °C = 303.15 K
α = Linear expansion coefficient = 3.04 × 10⁻⁴ K⁻¹
K = Volume comprehensibility = 4.52 × 10⁻⁵ atm⁻¹
Therefore,
75.3 -
= 
=
- 75.3 = 256.834 J/mol·K.
Given :
2NOBr(g) - -> 2NO(g) + Br2(g)
Initial pressure of NOBr , 1 atm .
At equilibrium, the partial pressure of NOBr is 0.82 atm.
To Find :
The equilibrium constant for the reaction .
Solution :
2NOBr(g) - -> 2NO(g) + Br2(g)
t=0 s 1 atm 0 0
1( 1-2x) 2x x
So ,

At equilibrium :
![K_{eq}=\dfrac{[NO]^2[br_2]}{[NOBr]^2}\\\\K_{eq}=\dfrac{0.18^2\times 0.9}{0.82^2}\\\\K_{eq}=0.043\ atm](https://tex.z-dn.net/?f=K_%7Beq%7D%3D%5Cdfrac%7B%5BNO%5D%5E2%5Bbr_2%5D%7D%7B%5BNOBr%5D%5E2%7D%5C%5C%5C%5CK_%7Beq%7D%3D%5Cdfrac%7B0.18%5E2%5Ctimes%200.9%7D%7B0.82%5E2%7D%5C%5C%5C%5CK_%7Beq%7D%3D0.043%5C%20atm)
Hence , this is the required solution .
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