Toxaphene is a kind of pesticides used to protect crops specially cotton crops.
It is present in both solid and gas form.
It has a piney odor.
The physical appearance of toxaphene is yellow in colour amber waxy form.
It is an organochloride insecticide.
In 1940 it was manufactured.
It is a different composition of 670 chemicals.
According to questions,
Given,
Mass of toxaphene = 10^-5 gm
Mass of soil = 100 gm
Toxaphene soil concentrations = 10^-5 / 100 = 10^-7 gm/gm
1 gm/gm = 109 ppb
Concentration in units of ppb =10^-7 * 109 ppb = 100 ppb
To know more about toxaphene here :
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Calculate its molar solubility in a saturated aqueous solution that is also 0.050 M in fluoride ion, F-. Ksp = (x)(2x + 0.05)2. 2x = 4.210 4
Answer:
Equilibrium constant expression for 
:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{[\mathrm{H_2CO_3}]}{\left[\mathrm{H^{+}\, (aq)}\right]^{2} \, \left[\mathrm{CO_3}^{2-}\right]}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Capprox%20%5Cfrac%7B%5B%5Cmathrm%7BH_2CO_3%7D%5D%7D%7B%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%5C%2C%20%28aq%29%7D%5Cright%5D%5E%7B2%7D%20%5C%2C%20%5Cleft%5B%5Cmathrm%7BCO_3%7D%5E%7B2-%7D%5Cright%5D%7D)
.
Where
, 
, and 
denote the activities of the three species, and ![[\mathrm{H_2CO_3}]](https://tex.z-dn.net/?f=%5B%5Cmathrm%7BH_2CO_3%7D%5D)
, ![\left[\mathrm{H^{+}}\right]](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%7D%5Cright%5D)
, and ![\left[\mathrm{CO_3}^{2-}\right]](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathrm%7BCO_3%7D%5E%7B2-%7D%5Cright%5D)
denote the concentrations of the three species.
Explanation:
<h3>Equilibrium Constant Expression</h3>
The equilibrium constant expression of a (reversible) reaction takes the form a fraction.
Multiply the activity of each product of this reaction to get the numerator.
is the only product of this reaction. Besides, its coefficient in the balanced reaction is one. Therefore, the numerator would simply be 
.
Similarly, multiply the activity of each reactant of this reaction to obtain the denominator. Note the coefficient "
" on the product side of this reaction. 
is equivalent to 
. The species 
appeared twice among the reactants. Therefore, its activity should also appear twice in the denominator:
.
That's where the exponent "" in this equilibrium constant expression came from.
Combine these two parts to obtain the equilibrium constant expression:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \quad\begin{matrix}\leftarrow \text{from products} \\[0.5em] \leftarrow \text{from reactants}\end{matrix}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Cquad%5Cbegin%7Bmatrix%7D%5Cleftarrow%20%5Ctext%7Bfrom%20products%7D%20%5C%5C%5B0.5em%5D%20%5Cleftarrow%20%5Ctext%7Bfrom%20reactants%7D%5Cend%7Bmatrix%7D)
.
<h3 /><h3>Equilibrium Constant of Concentration</h3>
In dilute solutions, the equilibrium constant expression can be approximated with the concentrations of the aqueous "
" species. Note that all the three species here are indeed aqueous. Hence, this equilibrium constant expression can be approximated as:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{\left[\mathrm{H_2CO_3\, (aq)}\right]}{\left[\mathrm{H^{+}\, (aq)}\right]^2\cdot \left[\mathrm{{CO_3}^{2-}\, (aq)}\right]}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Capprox%20%5Cfrac%7B%5Cleft%5B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%5Cright%5D%7D%7B%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%5C%2C%20%28aq%29%7D%5Cright%5D%5E2%5Ccdot%20%5Cleft%5B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%5Cright%5D%7D)
.
Balance and graduate cylinder
The correct answer is: by the transfer of one or more electrons from one atom to another.
