Question

Consider the following reaction at 298K.

Answer 1

The true statements are;

• K < 0
• Eocel  < 0

What is a redox reaction?

We define a redox reaction as one in which a specie is oxidized and another is reduced.

Now;

Eo cell = cell potential = -0.13 V - (+0.34 V) = -0.47 V

n =number of moles of electrons = 2 mole of electrons

K = equilibrium constant

ΔG = change in free energy

Eo cell = 0.0592/n log K

-0.47 =  0.0592/2 log K

log K =  -0.47  * 2/0.0592

K = 1.3 * 10^-16

ΔG = -nFEo cell

ΔG = -(2 * 96500 * -0.47)

ΔG = 90.7kJ

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