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2 years ago

synergistic interlayer and defect engineering in vs2 nanosheets toward efficient electrocatalytic hydrogen evolution reaction

1 answer:

4 0

It is stated that VS2 nanosheets with abundant defects and an extended (001) interlayer spacing as large as 1.00 nm, which is a 74% expansion as compared to that (0.575 nm) of the pristine counterpart, may be produced using a straightforward one-pot solvothermal process.

For the electrocatalytic hydrogen evolution reaction (HER), the interlayer expanded VS2 nanosheets display exceptional kinetic metrics, including a low overpotential of 43 mV at a geometric current density of 10 mA cm2, a small Tafel slope of 36 mV dec1, and long-term stability of 60 h without any current fading. The performance is even comparable to that of the commercial Pt/C electrocatalyst and significantly better than that of the pure VS2 with a typical interlayer gap.

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Cost to supply enough vanillin is $3.2\$$

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As cost of 50 g vanillin is $112\$$ therefore cost of $(2.0\times 10^{-11}\times 5.0\times 10^{7}\times 28.32)g$ vanillin = $(2.0\times 10^{-11}\times 5.0\times 10^{7}\times 28.32\times 112)\$ = 3.2\$$

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3 years ago

How many grams of XeF6 are required to react with 0.579 L of hydrogen gas at 4.46 atm and 45°C in the reaction shown below?

natka813 [3]

Answer:

8.1433 g of XeF₆ are required.

Explanation:

Balanced chemical equation;

XeF₆ (s) + 3H₂ (g) → Xe (g) + 6HF (g)

Given data:

Volume of hydrogen = 0.579 L

Pressure = 4.46 atm

Temperature = 45 °C (45+273= 318 k)

Solution:

First of all we will calculate the moles of hydrogen

PV = nRT

n = PV/ RT

n = 4.46 atm × 0.579 L / 0.0821 atm. dm³. mol⁻¹. K⁻¹ × 318 K

n = 2.6 atm . L / 26.12 atm. dm³. mol⁻¹

n = 0.0995 mol

Mass of hydrogen:

Mass = moles × molar mass

Mass = 0.0995 mol × 2.016 g/mol

Mass = 0.2006 g

Now we will compare the moles of hydrogen with XeF₆ from balance chemical equation.

H₂ : XeF₆

3 : 1

0.0995 : 1/3× 0.0995 = 0.0332 mol

Now we will calculate the mass of XeF₆.

Mass = moles × molar mass

Mass = 0.0332 mol × 245.28 g/mol

Mass = 8.1433 g

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3 years ago