A reaction is in ____________ kinetics when the reaction rate depends only on enzyme concentration
1 answer:
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Answer:
Four possible isomers (1–4) for the natural product essramycin. The structure of compound 1 was attributed to essramycin by 1H NMR, 13C NMR, HMBC, HRMS, and IR experiments.
Explanation:
Three synthetic routes were used to prepare all four compounds (Figure 2A). All three reactions utilize 2-(5-amino-4H-1,2,4-triazol-3-yl)-1-phenylethanone (5) as the precursor, whereas each uses different esters (6–8) to construct the pyrimidinone ring. Isomer 1 was prepared by reaction A, which used triazole 5 and ethyl acetoacetate (6) in acetic acid. This was the reaction used in syntheses of essramycin by the Cooper and Moody laboratories.3,4 Reaction B produced compound 2 (minor product) and compound 3 (major product), which were separated chromatographically. This reaction allowed reagent 5 to react with ethyl 3-ethoxy-2-butenoate (7) in the presence of sodium in methanol, under reflux for 24 h. Compound 4 was prepared by reaction C, which was obtained by reflux of 5 and methyl 2-butynoate (8) in n-butanol.
Answer:
The mass percent of Al(OH)₃ is 15.3%
Explanation:
The reaction is:
Al(OH)₃ + 3HCl = AlCl₃ + 3H₂O
The excess acid is neutralized with a solution of sodium hidroxide, in the reaction:
NaOH + HCl = NaCl + H₂O
The total moles of HCl is:
From the second titration, the moles of excess of HCl is:
The difference between the total and excess of HCl, it can be know the moles that reacts with the aluminum hydroxide, is:
The ratio between HCl and Al(OH)₃ is 3:1. The MW for aluminum hydroxide is 78 g/mol, thus:
The percentage of Al(OH)₃ is:
%