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son4ous [18]
4 years ago
6

The following data were obtained from experiments to find the molecular formula of procaine, a local anesthetic, which contains

only carbon, hydrogen, nitrogen, and oxygen. Complete combustion of a 3.54g sample of procaine with excess O2 formed 8.58 g of CO2 and 2.70 g H2O. Another sample of mass 2.35 g was found to contain 0.279 g of N. The molar mass of procaine was found to be 236.Find the molar formula of procaine
Chemistry
1 answer:
Strike441 [17]4 years ago
3 0
All you really need to know is that H20 is water end of story
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Calculate E ° for the half‑reaction, AgCl ( s ) + e − − ⇀ ↽ − Ag ( s ) + Cl − ( aq ) given that the solubility product constant
antoniya [11.8K]

Answer: The value of E^{o} for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

          AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)

Its solubility product will be as follows.

       K_{sp} = [Ag^{+}][Cl^{-}]

Cell reaction for this equation is as follows.

     Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)

Reduction half-reaction: Ag^{+} + 1e^{-} \rightarrow Ag(s),  E^{o}_{Ag^{+}/Ag} = 0.799 V

Oxidation half-reaction: Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-},   E^{o}_{AgCl/Ag} = ?

Cell reaction: Ag^{+}(aq) + Cl^{-}(aq) \rightarrow AgCl(s)

So, for this cell reaction the number of moles of electrons transferred are n = 1.

    Solubility product, K_{sp} = [Ag^{+}][Cl^{-}]

                                               = 1.77 \times 10^{-10}

Therefore, according to the Nernst equation

           E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

At equilibrium, E_{cell} = 0.00 V

Putting the given values into the above formula as follows.

         E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

        0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}    

       E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}

                  = 0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}

                  = 0.577 V

Hence, we will calculate the standard cell potential as follows.

           E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}

       0.577 V = E^{o}_{Ag^{+}/Ag} - E^{o}_{AgCl/Ag}

       0.577 V = 0.799 V - E^{o}_{AgCl/Ag}

       E^{o}_{AgCl/Ag} = 0.222 V

Thus, we can conclude that value of E^{o} for the half-cell reaction is 0.222 V.

3 0
3 years ago
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