Wouldn’t it be half of each? For 36 I guess is 18 and 54 will be 27, (NOT SURE)
Answer:
True
Explanation:
We know that the zero-point-energy of a C-D system is quite lower than the zero point energy of the C-H bond so the C-D bond is stronger.
Kinetic isotope effect refers to the change in the rate of reaction owing to a change of one of the atoms of the reactants by replacing it with one of its isotopes.
Since we know that the C-D bond is stronger than the C-H bond, when we replace hydrogen with deuterium in a reaction's rate determining step we experience a little lag in the rate of reaction. This is referred to as the kinetic isotope effect in physical organic chemistry.
Answer:
See Explanation
Explanation:
An ionic bond occurs due to electrostatic attraction between a positively charged ion and a negatively charged ion.
A metal and a ligand are bound by a coordinate covalent bond or a dative bond. This bond occurs due to donation of electron pairs from ligands to available orbitals on metals.
The formation of coordinate bonds is evident when neutral molecules or negative ions with non bonding electrons donate same to empty metal orbitals. This is sometimes shown by an arrow pointing from the ligands to the metal center.
For instance; tetraammine copper II ion is formed when four ammonia molecules donate a lone pair each to available vacant orbitals of the copper metal center to form [Cu(NH3)4]^2+.
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