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AlekseyPX
3 years ago
11

Determine the percent ionization of a 0.145 m hcn solution.

Chemistry
1 answer:
iragen [17]3 years ago
5 0
When Ka of HCN  = 6.2x10^-10 

              HCN       H3O+      CN-
initial    0.145          0            0
change -X              +X          +X
final     (0.145-X)     +X          +X

Ka= [H3O+][CN]- / [HCN]
by substitution:
we can assume [HCN] = 0.145
6.2x10^-10 = X*X / (0.145) by solving this equation,
X = 9.5 x 10^-6 
∴ [ H3O+] = 9.5 X 10^-6 
∴percent ionization = [H3O+]/[HCN] *100
                               = 9.5X10^-6 / 0.145 *100
                               = 0.0066 %
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Determine the pHpH of an HFHF solution of each of the following concentrations. In which cases can you not make the simplifying
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The question is incomplete, complete question is :

Determine the pH of an HF solution of each of the following concentrations. In which cases can you not make the simplifying assumption that x is small? (K_a for HF is 6.8\times 10^{-4}.)

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Express your answer to two decimal places.

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The pH of an 0.280 M HF solution is 1.87.

Explanation:3

Initial concentration if HF = c = 0.280 M

Dissociation constant of the HF = K_a=6.8\times 10^{-4}

HF\rightleftharpoons H^++F^-

Initially

c          0            0

At equilibrium :

(c-x)      x             x

The expression of disassociation constant is given as:

K_a=\frac{[H^+][F^-]}{[HF]}

K_a=\frac{x\times x}{(c-x)}

6.8\times 10^{-4}=\frac{x^2}{(0.280 M-x)}

Solving for x, we get:

x = 0.01346 M

So, the concentration of hydrogen ion at equilibrium is :

[H^+]=x=0.01346 M

The pH of the solution is ;

pH=-\log[H^+]=-\log[0.01346 M]=1.87

The pH of an 0.280 M HF solution is 1.87.

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