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Pure substances are further broken down into elements and compounds. Mixture are physically combined structures that can be separated into their original components. A chemical substance is composed of one type of atom or molecule.
If you are taking about George Washington and George Washington Carver then the difference is one was a president and army leader (George Washington) while the other George Washington Carver was an inventor and botanist that is very well known for his inventions with peanuts. If not one is spelled with an r (George) and the other without (Geoge).
Barium nitrate and methane (CH4) are both soluble. They both will dissolve in water, however, barium nitrate will dissociate becoming barium 2+ ions and nitrate becoming NO3 1- ions. All nitrates are soluble and dissociate. CH4 is a weak base and does dissolves but doesn't dissociate. So in solubility terms.... they are both equally soluble just one happens to dissociate into its cations and anions. Hope this helps!
24518 is the answer to your queston