Answer:
Rutherfords
Explanation:
The model of the atom supported by Bohr's hydrogen experiment is the Rutherford's model of the atom.
Rutherford through his experiment on gold foil suggested the atomic model of the atom. The model posits that an atom has a small positively charged center(nucleus) where nearly all the mass is concentrated.
- Surrounding the nucleus is the large space containing electrons.
- In the Bohr's model of the atom, he suggested that the extranuclear space of the atom is made up of electrons in specific spherical orbits around the nucleus.
Answer:
2.1056L or 2105.6mL
Explanation:
We'll begin by calculating the number of mole in 10g of Na2CO3. This can be obtained as follow:
Molar mass of Na2CO3 = (23x2) + 12 + (16x3) = 106g/mol
Mass of Na2CO3 = 10g
Mole of Na2CO3 =.?
Mole = mass /molar mass
Mole of Na2CO3 = 10/106
Mole of Na2CO3 = 0.094 mole
Next, we shall determine the number of mole CO2 produced by the reaction of 0.094 mole of Na2CO3. This is illustrated below:
Na2CO3 + 2HCl —> 2NaCl + H2O + CO2
From the balanced equation above,
1 mole of Na2CO3 reacted to produce 1 mole of CO2.
Therefore, 0.094 mole of Na2CO3 will also react to 0.094 mole of CO2.
Next, we shall determine the volume occupied by 0.094 mole of CO2 at STP. This is illustrated below:
1 mole of a gas occupy 22.4L at STP. This implies that 1 mole CO2 occupies 22.4L at STP.
Now, if 1 mole of CO2 occupy 22.4L at STP, then, 0.094 mole of CO2 will occupy = 0.094 x 22.4 = 2.1056L
Therefore, the volume of CO2 produced is 2.1056L or 2105.6mL
DE = dH - PdV
<span>2 H2O(g) → 2 H2(g) + O2(g) </span>
<span>You can see that there are 2 moles of gas in the reactants and 3 moles of gas in the products. </span>
<span>1 moles of ideal gas occupies the same volume as 1 mole of any other ideal gas under the same conditions of temp and pressure. </span>
<span>Since it is done under constant temp and pressure that means the volume change will be equal to the volume of 1 mole of gas </span>
<span>2 moles reacts to form 3 moles </span>
<span>The gas equation is </span>
<span>PV = nRT </span>
<span>P = pressure </span>
<span>V = volume (unknown) </span>
<span>n = moles (1) </span>
<span>R = gas constant = 8.314 J K^-1 mol^-1 </span>
<span>- the gas constant is different for different units of temp and pressure (see wikki link) in this case temp and pressure are constant, and we want to put the result in an equation that has Joules in it, so we select 8.314 JK^-1mol^-1) </span>
<span>T = temp in Kelvin (kelvin = deg C + 273.15 </span>
<span>So T = 403.15 K </span>
<span>Now, you can see that PV is on one side of the equation, and we are looking to put PdV in our dE equation. So we can say </span>
<span>dE = dH -dnRT (because PV = nRT) </span>
<span>Also, since the gas constant is in the unit of Joules, we need to convert dH to Joules </span>
<span>dH = 483.6 kJ/mol = 483600 Joules/mol </span>
<span>dE = 483600 J/mol - (1.0 mol x 8.314 J mol^-1K-1 x 403.15 K) </span>
<span>dE = 483600 J/mol - 3351.77 J </span>
<span>dE = 480248.23 J/mol </span>
<span>dE = 480.2 kJ/mol </span>
Ibuprofen is synthesized by reacting ethyl 2-(4-isobutylphenyl)acetate with base, the base abstracts the acidic proton and enolate is formed which on reaction with diethyl carbonate generates diethyl 2-(4-isobutylphenyl)malonate
(A). diethyl 2-(4-isobutylphenyl)malonate on treatment with Base again looses the acidic proton and forms enolate. The enolate with treatment with Methyl Iodide yields diethyl 2-(4-isobutylphenyl)-2-methylmalonate
(B). diethyl 2-(4-isobutylphenyl)-2-methylmalonate on
hydrolysis give
Ibuprofen.
