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kozerog [31]
3 years ago
14

A 30.00 mL sample of HBr was titrated using 0.1756 M NaOH. Determine the concentration of the HBr sample if 17.52 mL of NaOH was

required to reach the endpoint in the titration.
Chemistry
1 answer:
postnew [5]3 years ago
5 0

<u>Answer:</u> The concentration of HBr sample is 0.1025 M

<u>Explanation:</u>

To calculate the concentration of acid, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is HBr

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=1\\M_1=?M\\V_1=30.00mL\\n_2=1\\M_2=0.1756M\\V_2=17.52mL

Putting values in above equation, we get:

1\times M_1\times 30.00=1\times 0.1756\times 17.52\\\\M_1=\frac{1\times 0.1756\times 17.52}{1\times 30.00}=0.1025M

Hence, the concentration of HBr sample is 0.1025 M

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when 10.00 g of phosphorus reacts with oxygen, it produces 17.77 g of a phosphorus oxide. This phosphorus oxide was found to hav
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P(s)         +        O₂(g)------------------------------------⇒ PₓOₙ (g)

10g                     (17.77-10)g                                    17.77g

10g                        7.77g                                          17.77g  (gramme ratio)

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The molecular mass of Oxygen atom (O) = 16g/mole

Mole ratio is given by:

P              :             O

10/31                    7.77/16

0.3226       :         0.4856                Mole ratio---------------------------- (1)

Divide (1)  through by 0.3226

 1                 :        1.5-------------------------------------------- (2)

From  (2), the empirical formula for Phosphorus oxide :

Empirical formula = P₁O₁.₅

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Since the molecular formula is a multiple of the empirical formula we have

Molecular formula = (PO₁.₅)ₙ----------------------------------- (3)

Since we are given the molecular mass of the oxide formed, we have:

(PO₁.₅)ₙ = 220-----------------------------(4)

[31 + (16 x 1.5)] x n = 220

[31 + 24]n = 220

55n =220

n = 4

Substituting into (3), we have :

Molecular formula = (PO₁.₅)₄

                               = P₄O₆

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