This problem is asking for the equilibrium constant at two different temperatures by describing the chemical equilibrium between gaseous nitrogen, oxygen and nitrogen monoxide at 25 °C and 1496 °C as the room temperature and the typical temperature inside the cylinders of a car's engine respectively:
N₂(g) + O₂(g) ⇄ 2 NO(g)
Thus, the calculated equilibrium constants turned out to be 6.19x10⁻³¹ and 9.87x10⁻⁵ at the aforementioned temperatures, respectively, according to the following work:
There is a relationship between the Gibbs free energy, enthalpy and entropy of the reaction, which leads to the equilibrium constant as shown below:

Which means we can calculate the enthalpy and entropy of reaction and subsequently the Gibbs free energy and equilibrium constant. In such a way, we calculate these two as follows, according to the enthalpies of formation and standard entropies of N₂(g), O₂(g) and NO(g) since these are assumed constant along the temperature range:

Then, we calculate the Gibbs free energy of reaction at both 25 °C and 1496 °C:

And finally, the equilibrium constants derived from the general Gibbs equation and Gibbs free energies of reaction:
![K=exp(-\frac{\Delta _rG}{RT} )\\\\K_{25\°C}=exp[-\frac{172420 J/mol}{(8.3145\frac{J}{mol*K})(298.15K)} ]=6.19x10^{-31}\\\\K_{1496\°C}=exp[-\frac{135650J/mol}{(8.3145\frac{J}{mol*K})(1769K)} ]=9.87x10^{-5}](https://tex.z-dn.net/?f=K%3Dexp%28-%5Cfrac%7B%5CDelta%20_rG%7D%7BRT%7D%20%29%5C%5C%5C%5CK_%7B25%5C%C2%B0C%7D%3Dexp%5B-%5Cfrac%7B172420%20J%2Fmol%7D%7B%288.3145%5Cfrac%7BJ%7D%7Bmol%2AK%7D%29%28298.15K%29%7D%20%5D%3D6.19x10%5E%7B-31%7D%5C%5C%5C%5CK_%7B1496%5C%C2%B0C%7D%3Dexp%5B-%5Cfrac%7B135650J%2Fmol%7D%7B%288.3145%5Cfrac%7BJ%7D%7Bmol%2AK%7D%29%281769K%29%7D%20%5D%3D9.87x10%5E%7B-5%7D)
Learn more:
Choose five elements from the periodic table and arrange them according to increasing atomic radii increasing ionization energy increasing electronegativity in increasing metallic property
Neutrons the way this question is setup the atom would not be able to be neutral
Solution :
An
reaction is a type of
in organic chemistry where the enol or an enolate ion reacts with the carbonyl compound and forms a
-hydroxyaldehyde or a
-hydroxyketone, and then followed by a dehydration to give conjugated enone.
Benzaldehyde reacts with methylketone and forms two products:
Answer:
The new temperature is 1596 C.
Explanation:
Charles's Law indicates that for a given sum of gas at constant pressure, as the temperature increases, the volume of the gas increases, and as the temperature decreases, the volume of the gas decreases.
Statistically, Charles's law is a law that says that when the amount of gas and pressure are kept constant, the ratio that exists between the volume and the temperature will always have the same value:

Being an initial state 1 and a final state 2, it is fulfilled:

In this case:
- V1= 25 L
- T1= 350 C= 623 K (being 0 C= 273 K)
- V2= 75 L
- T2= ?
Replacing:

Solving:


T2= 1869 K= 1596 C
<u><em>The new temperature is 1596 C.</em></u>