Answer:
a. 7278 K
b. 4.542 × 10⁻³¹
Explanation:
a.
Let´s consider the following reaction.
N₂(g) + O₂(g) ⇄ 2 NO(g)
The reaction is spontaneous when:
ΔG° < 0 [1]
Let's consider a second relation:
ΔG° = ΔH° - T × ΔS° [2]
Combining [1] and [2],
ΔH° - T × ΔS° < 0
ΔH° < T × ΔS°
T > ΔH°/ΔS°
T > (180.5 × 10³ J/mol)/(24.80 J/mol.K)
T > 7278 K
b.
First, we will calculate ΔG° at 25°C + 273.15 = 298 K
ΔG° = ΔH° - T × ΔS°
ΔG° = 180.5 kJ/mol - 298 K × 24.80 × 10⁻³ kJ/mol.K
ΔG° = 173.1 kJ/mol
We can calculate the equilibrium constant using the following expression.
ΔG° = - R × T × lnK
lnK = - ΔG° / R × T
lnK = - 173.1 × 10³ J/mol / (8.314 J/mol.K) × 298 K
K = 4.542 × 10⁻³¹
Mass is always conserved in a physical change. Energy may be released or absorbed when a substance changes from one physical state to another. In a chemical change, a chemical reaction yields a completely new substance. A substance's particles are changed during a chemical reaction.
Answer:
Moles of NO₂ = 0.158
Explanation:
SO 2 ( g ) + NO 2 ( g ) ⇄ SO 3 ( g ) + NO ( g )
According to the law of mass equation
= ![\frac{[SO_{3} ][NO]}{[SO_{2}][NO_{2} ]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BSO_%7B3%7D%20%5D%5BNO%5D%7D%7B%5BSO_%7B2%7D%5D%5BNO_%7B2%7D%20%20%5D%7D)
⇒ 3.10 = ![\frac{(1.00)(1.00)}{(2.30) [NO_{2} ]}](https://tex.z-dn.net/?f=%5Cfrac%7B%281.00%29%281.00%29%7D%7B%282.30%29%20%5BNO_%7B2%7D%20%5D%7D)
At equilibrium [SO₃] = [NO]
⇒ [NO₂] = 
⇒ [NO₂] = 0.158
So. number of moles of NO₂ at equilibrium added = 0.158
<span>The correct answer is 3: 0.10 M K3PO4(aq). The higher the concentration (or molarity), the higher the boiling point. Thus, the solution with the most moles will have the highest boiling point. SO4, PO4, and NO3 are all polyatomic ions, so by definition, they only have one mole. In K3PO4, K3 has 3 moles and PO4 has 1 mole, meaning all together it has 4 moles (more than any of the other options).</span>
