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Ilia_Sergeevich [38]
3 years ago
9

The element lead (pb) consists of four naturally occurring isotopes with atomic masses 203.97302,205.97444,206.97587, n 207.9766

3 amu. the relative abundances of these four isotopes are 1.4,24.1,22.1, and 52.4 %, respectively. write the most common isotope of lead in two ways
Chemistry
1 answer:
Marina CMI [18]3 years ago
3 0

The method of determining the most common isotope of lead is by determining the average atomic mass. The formula for determining the average atomic mass is:

average atomic mass = \Sigma {percent abundance}\times {atomic mass}

Substituting the values in the formula:

average atomic mass = \frac{{203.97302}\times {1.4}+{205.9744}\times {24.1}+{206.97587}\times {22.1}+{207.97663}\times {52.4}}{100}

average atomic mass = \frac{285.562228+4963.984004+4574.166727+10897.975412}{100}

average atomic mass = \frac{20721.688371}{100} = 207.22 amu

The most common isotope of lead is:

Lead - 207.22 amu

The atomic symbol of lead is Pb. The atomic number of Pb is 82.

So, the the most common isotope of lead can be written as:

_{207.22}^{82}Pb and Lead - 207.22 amu.

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Calculate the pH of each of the following solutions: (a) 0.1000M Propanoic acid (HC3H5O2, Ka= 1.3x10-5 ) (b) 0.1000M sodium prop
jek_recluse [69]

(a) The pH of 0.1000 M propanoic acid (HC3H5O2) is 2.9.

(b) The pH of 0.1000 M sodium propanoate (NaC3H5O2) is 8.9.

(c) The pH of 0.1000 M propanoic acid (HC3H5O2) and 0.1000 M sodium propanoate (NaC3H5O2) is 4.9.

<h3>Further explanation:</h3>

(a)

Given information:

The value of acid ionization constant for propanoic acid is  1.3 x 10^{-5} .

The initial concentration of propanoic acid is  .

To calculate:

The pH of 0.1000 M propanoic acid solution.

Solution:

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

 

The expression for acid dissociation constant is,

                                                            …… (1)

Here,

 is ionization constant of propanoic acid.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydronium ion.

 is the equilibrium concentration of propanoic acid.

ICE table (1):

 

Refer ICE table (1),

 

Substitute the values form the ICE table (1) in equation (1).

 

The approximation x is very small is valid. Therefore, the value of x can be neglected. Above equation can be modified as,

 

Rearrange above equation for x.

                                                                                                           …… (2)

Substitute   for   in equation (2) to calculate the value of x.

 

Therefore, from the ICE table (1) the concentration of hydronium ion is,

 .

The negative logarithm of hydronium ion concentration is defined as the pH of the solution. Mathematically,

                                                                                                               …… (3)

Substitute    for    in equation (3) to calculate the pH of the solution.

 

(b)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate solution.

Solution:

Sodium propanoate  is conjugate base of weak propanoic acid. It undergoes hydrolysis in water to yield hydroxide ion in the solution as follows:

                                                        …… (4)

Propanoic acid  is a weak acid. It ionizes partially in water as follows:

                                                       …… (5)

Dissociation reaction for water is written as follows:

                                                                                       …… (6)

From equation (4), (5), and (6) the relationship between   and   is,

                                                                                                                              …… (7)

Substitute   for   and   for   in equation (7).

 

ICE table (2):

 

The expression for base dissociation constant is,

                                                                                                     …… (8)

Here,

is base ionization constant.

is the equilibrium concentration of propanoate ion.

is the equilibrium concentration of hydroxide ion.

 is the equilibrium concentration of propanoic acid.

From the ICE table (2),

 

Substitute the values form the ICE table (2) in equation (8).

 

The approximation y is very small is valid. Therefore, the value of y can be neglected. Above equation can be modified as,

 

Rearrange above equation for y.

                                                                                                           …… (9)

Substitute   for   in equation (9) to calculate the value of y.

 

Therefore, from the ICE table (2) the concentration of hydroxide ion is,

 

The negative logarithm of hydroxide ion concentration is defined as pOH of the solution. Mathematically,

                                                                                                           …… (10)

Substitute    for    in equation (10) to calculate pOH of the solution.

 

The relation between pH and pOH is as follows:

                                                                                                                   …… (11)

Substitute 5.057 for pOH in equation (11) to calculate the pH of the solution.

 

(c)

Given information:

The value of acid ionization constant for propanoic acid is  .

The initial concentration of sodium propanoate is  .

The initial concentration of sodium propanoate is  .

To calculate:

The pH of 0.1000 M sodium propanoate and 0.1000 M propanoic acid solution.

Solution:

Propanoic acid is a weak acid, and sodium propanoate is salt of the conjugate base of propanoic acid. Thus, propanoic acid and sodium propanoate will form a buffer system.

The pH of the buffer solution can be determined with the help of the Henderson-Hasselbalch equation. Mathematically,

 

For propanoic acid and sodium propanoate buffer system, the Henderson-Hasselbalch equation can be modified as,

                                                                                               …… (12)

The negative logarithm of acid ionization constant is equal to  .

                                                                                                                …… (13)

Substitute   for  in equation (13).

 

Substitute    for  ,   for   and 4.9 for    in equation (12).

 

Learn more:

1. About Henderson-Hasselbalch equation brainly.com/question/12999557

2. Learn more about how to calculate moles of the base in given volume brainly.com/question/4283309

Answer details:

Grade: Senior School

Subject: Chemistry

Chapter: Ionic equilibria

Keywords: ionic equilibrium, propanoic acid, sodium propanoate, ionization constant, weak acid, conjugate base, equilibrium concentration, hydronium ion, hydroxide ion, pH, pOH, ICE table, negative logarithm, buffer solution, Henderson-Hasselbalch equation, 0.1000 M, 4.9, 8.9, 2.9.

3 0
4 years ago
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Explanation:

5 0
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2H2 + O2 → 2H2O
pantera1 [17]
Okay
Mr (H2O)= 18g
therefore moles of H2O
is 720.8/18= 40.04mol
the ratio of H2 to O2 to H2O is
2 : 1 : 2
so moles of H2 is same as H2O here
H2= 40.04moles

moles of O2 is half
so 40.04 x 0.5
20.02moles

grams of O2 is
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3 years ago
Derive an expression for the molar mass of a gas starting with its density?
notka56 [123]

Answer:

The relationships between molar mass and density for a monoatomic gas can be easy.  

The Ideal Gas Law, PV = nRT can be arranged so that n moles equals the mass/molar mass of the gas to become,

PV =  

M

mRT

​  

 

where m is the mass and M is the molar mass.

M =  

PV

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​  

, if you hold the temperature of the gas constant the equation reduces to the Boyle's law or  

PV

m

​  

 

The mass will be constant assuming the container is closed and so the gas cannot be escaped so, PV will be constant.  

D =  

V

m

​  

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Explanation:

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