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Leokris [45]
3 years ago
13

What reaction conditions most effectively convert a carboxylic acid to a methyl ester

Chemistry
2 answers:
ycow [4]3 years ago
4 0

Answer:

Fischer Esterification

Explanation:

Fischer esterification or Fischer-Speier esterification is a carboxylic esterification reaction that uses an inorganic acid as a catalyst, mainly sulfuric acid (H2SO4).

The carboxylic acids are usually too weak acids, so they have little tendency to yield the proton (H +) that they lose in the esterification.

A stronger acid, such as sulfuric acid, behaves like a proton donor and facilitates the esterification reaction.

First, sulfuric acid injects a proton into the carboxyl group

The alcohol molecule, R’-OH, has an electron-rich oxygen atom, is attracted to the protonated carboxylic structure

This complex is not very stable and stabilizes towards the most favorable energy molecule, which is the ester, releasing a water molecule and a proton (H +). The proton is then used to regenerate sulfuric acid

dem82 [27]3 years ago
4 0

Answer: The convenient and efficient sonochemical method for methyl esterification of carboxylic acids reaction conditions are ;

• catalyzation by polymer-supported triphenylphosphine (0.1 eq. PS-PPh3)

• in the presence of 2,4,6-trichloro-1,3,5-triazine (1.0 eq. TCT) and Na2CO3 (2.0 eq. )

• Temperature 50°C for 10 - 30 mins

Explanation:

Methyl esters of various carboxylic acids bearing reactive hydroxyl groups as well as acid- or base-labile functionalities could be rapidly prepared within short times in good to excellent yields in high purities without column chromatography.

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Calculate the mass of MgCO3 precipitated by mixing 10.00 mL of a 0.200 M Na2CO3 solution with 5.00 mL of a 0.0450 M Mg(NO3)2 sol
aliya0001 [1]

Answer:

1.90 g

Explanation:

When we are making calculations based on chemical reactions, we need first to have a balanced chemical equation.

From there we can determine the mass of the product MgCO₃ in this question.

Na₂CO₃   +   Mg(NO₃)₂     ⇒   2 NaNO₃   + MgCO₃ ( double decomposition )

0.200 M   0.0450 M                                        ?

10.0           5.00 mL  

Now we know the volume and concentration of Mg(NO₃)₂,and Na₂CO₃ so we must compute their number of moles to determine the limiting reagent, if any.From there determine moles and mass of MgCO₃ produced.

First lets convert the volume of  Mg(NO₃)₂and Na₂CO₃ to liters:

5.00 mL x ( 1 L/1000 mL ) =    5.00 x 10⁻³ L

10.00 mL x ( 1L/ 1000 mL ) = 1.000 x 10 ⁻² L

# mol Mg(NO₃)₂ = ( 0.0450 mol /L  ) x 5.00 x 10⁻³ L

                                         = 2.25 x 10⁻⁴ mol Mg(NO₃)₂

# mol Na₂CO₃ = ( 0.200 mol / L ) x 1 x 10⁻² L  

                                         = 2.000 x 10⁻³  mol Na₂CO₃

Calculation limiting reagent:

= 2.25 x 10⁻⁴ mol Mg(NO₃)₂ x ( 1 mol Na₂CO₃ / mol  Mg(NO₃)₂ )

= 2.25 x 10⁻⁴ mol  Na₂CO₃ required to react

Therefore, our limiting reagent is Mg(NO₃)₂ since we require  2.25 x 10⁻⁴ mol  Na₂CO₃  to react completely with  2.25 x 10⁻⁴Mg(NO₃)₂, and we have excess of it.

# mol MgCO₃ produced

= 2.25 x 10⁻⁴ mol  Mg(NO₃)₂ x ( 1 mol MgCO₃ / 1 mol Mg(NO₃)₂ )

= 2.25 x 10⁻⁴ mol  MgCO₃

Now that we have the moles of MgCO₃, we can obtain its mass by multiplying its molar mas ( 84.31 g/mol ):

2.25 x 10⁻⁴ mol  MgCO₃ x   84.31 g/mol  = 1.90 g

7 0
3 years ago
2. Ultraviolet radiation has a frequency of 6.8 x 10'5Hz. Calculate the energy, in
Gnoma [55]

Answer:

E=4.5\times 10^{-18}\ J

Explanation:

It is given that, the frequency of Ultraviolet radiation is 6.8\times 10^{15}\ Hz

We need to find the energy of the photon. The formula for the energy of a photon is given by :

E=hf\\\\\text{Where h is Planck's constant}\\\\E=6.63\times 10^{-34}\times 6.8\times 10^{15}\\\\E=4.5\times 10^{-18}\ J

So, the energy of the photon is 4.5\times 10^{-18}\ J.

3 0
3 years ago
What is photosynthesis?​
sertanlavr [38]

Explanation:

the process by which green plants and some other organisms use sunlight to synthesize foods from carbon dioxide and water. Photosynthesis in plants generally involves the green pigment chlorophyll and generates oxygen as a byproduct.

5 0
3 years ago
Read 2 more answers
When rubidium metal is exposed to air, two atoms of rubidium, Rb, combine with one atom
Eddi Din [679]

2.1653 g

Explanation:

The molar mass of Rubidium is;

85.468 g/mol

Therefore the moles of Rubidium that reacted with oxygen is;

1.98 / 85.468

= 0.0232 moles

If every two moles of Rubidium reacts with one mole of oxygen then the amount of oxygen consumed in the chemical reaction is;

0.5 * 0.0232

= 0.0116 moles

The molar mass of an oxygen atom is 16 g/mole. Then the amount of O in grams consumed is;

0.0116 * 16

=0.1853 g

The final weight of the Rubidium II Oxide is;

1.98 + 0.1853

= 2.1653 g

8 0
3 years ago
1. Fill in the best answer for each of the following: a) ________________________ is the capacity to do work or to supply heat.
user100 [1]

Answer:

A. Energy

B. Chemical potential

C. Endothermic reaction

D.The law of conservation of mass

E. Transfers of energy

5 0
3 years ago
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