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oee [108]
3 years ago
7

Question 14 (1 point)

Chemistry
1 answer:
marta [7]3 years ago
3 0

Answer:

Molarity = 1.4 M

Explanation:

Given data:

Mass of LiCl = 15.25 g

Volume of solution = 250 mL (250/1000 = 0.25 L)

Molarity of solution = ?

Solution:

Molarity is used to describe the concentration of solution. It tells how many moles are dissolve in per litter of solution.

Formula:

Molarity = number of moles of solute / L of solution

Now we will calculate the number of moles of LiCl.

Number of moles = mass/molar mass

Number of moles = 15.25 g/ 42.39 g/mol

Number of moles = 0.36 mol

Molarity:

Molarity = 0.36 mol / 0.25 L

Molarity = 1.4 M           (M= mol/L)

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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are
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<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

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Volume of 14.00g of nitrogen at 5.64atm and 315k
VikaD [51]

The volume of a 14.00g of nitrogen at 5.64atm and 315K is 4.59L.

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An ideal gas is a hypothetical gas, whose molecules exhibit no interaction, and undergo elastic collision with each other and with the walls of the container.

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V = 25.86 ÷ 5.64

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Therefore, 4.59L is the volume of the gas

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