A 20.0-liter flask contains a mixture of argon at 0.72 atmosphere and oxygen at 1.65 atmospheres. What is the total pressure in
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Answer:
a) pH will be 12.398
b) pH will be 4.82.
Explanation:
a) The moles of NaOH added = molarity X volume (L) = 2 X 0.01 = 0.02 moles
The total volume after addition of pure water = 0.780+0.01 = 0.79 L
The new concentration of /NaOH will be:
the [OH⁻] = 0.025
pOH = -log [OH⁻] = 1.602
pH = 14 -pOH = 12.398
b) The buffer has butanoic acid and butanoate ion.
i) Before addition of NaOH the pH will be calculated using Henderson Hassalbalch's equation:
pKa=
ii) on addition of base the pH will increase.
The density : 21.63 g/L
<h3>Further explanation</h3>The gas equation can be written
where
P = pressure, atm
V = volume, liter
n = number of moles
R = gas constant = 0.08206 L.atm / mol K
T = temperature, Kelvin
T = 65+273=338 K
P=2.36 atm
MW Iodine gas (I₂)=254
The density :