Answer:
K(48.5°C) = 1.017 E-8 s-1
Explanation:
- CH3Cl + H2O → CH3OH + HCl
at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1
at T2 = 48.5°C (321.5 K) ⇒ K2 = ?
Arrhenius eq:
- K(T) = A e∧(-Ea/RT)
- Ln K = Ln(A) - [(Ea/R)(1/T)]
∴ A: frecuency factor
∴ R = 8.314 E-3 KJ/K.mol
⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)
⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)
(1)/(2):
⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)
⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)
⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)
⇒ Ln (K1/K2) = - 3.422
⇒ K1/K2 = e∧(-3.422)
⇒ (3.32 E-10 s-1)/K2 = 0.0326
⇒ K2 = (3.32 E-10 s-1)/0.0326
⇒ K2 = 1.017 E-8 s-1
<span>1962.252(a)
whenever the material is dropped from 20feet to any poiny lying outside the exterior wall of building, an enclosed chute of wood, or equivalent material. For the purpose of paragraph, an enclose chute is a slide, closed in all sides, through which material is placed from high plac eto lower one.
1962.252(b)
when the disposal is dropped through holes in the floor without the use of chute, the area onto which the material is dropped shall be completely enclosed with barricades not less than 42 inch high and not less than 6 feet back from the projected edge of of the opening valve. signs warning of hazards of falling material shall be posted at each level.
1962.252(c)
All scrap lumper, waste material, and rubbish shall be removed from the immediate work area as the work progresses.
1962.252(d)
Disposal of waste material or debris by burning shall comply with local fire regulation
1962.252(e)
All sovent waste, oily rags, and flammable liquid should be kept in fire resistant covered container until removed from work site.</span>
Answer: The partial pressure of oxygen in the mixture is 321 mm Hg
Explanation:
According to Dalton's law, the total pressure is the sum of individual pressures.
Given : 
= total pressure of gases = 752 mm Hg
= partial pressure of Helium = 234 mm Hg
= partial pressure of nitrogen = 197 mm Hg
= partial pressure of oxygen = ?
Putting in the values we get:
The partial pressure of oxygen in the mixture is 321 mm Hg
