Answer:
Explanation:
Given parameters;
pH = 8.74
pH = 11.38
pH = 2.81
Unknown:
concentration of hydrogen ion and hydroxyl ion for each solution = ?
Solution
The pH of any solution is a convenient scale for measuring the hydrogen ion concentration of any solution.
It is graduated from 1 to 14
pH = -log[H₃O⁺]
pOH = -log[OH⁻]
pH + pOH = 14
Now let us solve;
pH = 8.74
since pH = -log[H₃O⁺]
8.74 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 1.82 x 10⁻⁹mol dm³
pH + pOH = 14
pOH = 14 - 8.74
pOH = 5.26
pOH = -log[OH⁻]
5.26 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] = 5.5 x 10⁻⁶mol dm³
2. pH = 11.38
since pH = -log[H₃O⁺]
11.38 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 4.17 x 10⁻¹² mol dm³
pH + pOH = 14
pOH = 14 - 11.38
pOH = 2.62
pOH = -log[OH⁻]
2.62 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] =2.4 x 10⁻³mol dm³
3. pH = 2.81
since pH = -log[H₃O⁺]
2.81 = -log[H₃O⁺]
[H₃O⁺] = 10⁻
[H₃O⁺] = 1.55 x 10⁻³ mol dm³
pH + pOH = 14
pOH = 14 - 2.81
pOH = 11.19
pOH = -log[OH⁻]
11.19 = -log[OH⁻]
[OH⁻] = 10
[OH⁻] =6.46 x 10⁻¹²mol dm³
atomic number is equal to proton number
so the proton number will be 87
Answer:
The correct option is: Carbonate ion < Carbon dioxide < Carbon monoxide
Explanation:
Bond energy is defined as the average energy needed to break a chemical covalent bond and signifies the strength of chemical covalent bond.
The bond strength of a covalent bond depends upon the <u>bond length and the bond order.</u>
Carbon monoxide molecule (CO) has two covalent bond and one dative bond. Bond order 2.6
Carbon dioxide (CO₂) has two carbon-oxygen (C-O) double bonds of equal length. Bond order 2.0
Carbonate ion (CO₃²⁻) has three C-O partial double bonds. Bond order 1.5
Also, the bond length is <u>inversely proportional to the bond order and bond strength.</u>
Therefore, <u>order of C-O bond length:</u> Carbon monoxide<Carbon dioxide<Carbonate ion
<u>Order of C-O bond order</u>: Carbonate ion<Carbon dioxide<Carbon monoxide
<u>Order of C-O bond strength or energy</u><u>: Carbonate ion<Carbon dioxide<Carbon monoxide</u>
From the given pH, we calculate the concentration of H+:
[H+] = 10^-pH = 10^-5.5
We then use the volume to solve for the number of moles of H+:
moles H+ = 10^-5.5M * 4.3x10^9 L = 13598 moles
From the balanced equation of the neutralization of hydrogen ion by limestone written as
CaCO3(s) + 2H+(aq) → Ca2+(aq) + H2CO3(aq)
we use the mole ratio of limestone CaCO3 and H+ from their coefficients, which is 1 mole of CaCO3 is to react with 2 moles of H+, to compute for the mass of the limestone:
mass CaCO3 = 13598mol H+(1mol CaCO3/2mol H+)
(100.0869g CaCO3/1mol CaCO3)(1kg/1000g)
= 680 kg
1.6456 x 10^3 (ten to the third power)
