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LuckyWell [14K]
3 years ago
11

Consider the following set of ions: Al3+; Li+, Rb+, [(C4H9)4N+].

Chemistry
1 answer:
krok68 [10]3 years ago
3 0

Hey there!:

a) Cations which are lowest size generally forms adopts more number of water molecules around it. Such kind of Cations forms largest hydrated ions. Among given cations, Li+ is smallest one and (C4H9)4N+ is largest one. So, Li+ ion forms largest hydrated ion.

b) Organic ligands or alkyl chains contained Cations are hydrophobic in nature due to its low polar nature. Among given (C₄H₉)4N⁺ cation is hydrophobic in nature.

c) Size of cation inversely proportional to the hydrated sphere or number of water molecules attached. So, in the given Cations  (C₄H₉)4N⁺ is largest cation which attaches fewest water molecules.

d) Charge on the cation makes it more electrostatic maker. But size is inversily proportional to electrostatic property. (C₄H₉)4N⁺ is electrostatic structure breaker.

e) Al⁺³ has highest charge. So it is most electrostatic structure maker.

Hope this helps!

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