Answer:
C. Hb binds O2 more tightly than Mb.
Explanation:
<u>Hb and Mb are both oxygen carrier protiens which contain the heme group. Hb has 4 heme units in 1 moleucle which work via coperative effect. On the other hand, Mb has only one heme unit. </u>
<u>From above theory, statement A and B are correct.</u>
<u>Although the heme group of the Mb is identical to those of Hb, Mb has a higher affinity for carrying oxygen than hemoglobin.</u>
<u>Hence, Statement C is wrong.</u>
Thats why the function of hemoglobin is to transport oxygen and that of myoglobin is to store oxygen.
<u>When a curve is plotted between oxygen accepted and the pressure of the oxygen, Hb shows sigmoidal, whereas Mb shows hyperbolic oxygen saturation curves.</u><u> The statement D is correct.</u>
<u>Bohr effect and various factors decribe the statement : Hb-oxygen binding is dependent on physiological changes in pH, whereas Mb-oxygen binding is not. </u><u>The statement E is also correct.</u>
Answer:
8.20 % → Percent yield reaction
Explanation:
To find the percent yield of reaction we apply this:
(Produced yield / Theoretical yield) . 100 = %
Produced yield = 112.9 g
Theoretical yield = 1375.5 g
We replace → (112.9g / 1375.5 g) . 100
8.20 % → Percent yield reaction
Answer:The product formed on reaction with hydroxide ion as nucleophile is 2R-hexane-2-ol.
The product formed on reaction with water would be a 50:50 mixture of
2S-hexane-2-ol. and 2R-hexane-2-ol.
Explanation:
2S-iodohexane on reactiong with hydroxide ion would undergo SN² substitution reaction that is substitution bimolecular. Hydroxide ion has a negative charge and hence it is a quite good nucleophile .
The rate of a SN² reaction depends on both the substrate and nucleophile . Here the substrate is a secondary carbon center having Iodine as a leaving group.SN² reaction takes place here as hydroxide ion is a good nucleophile and it can attack the secondary carbon center from the back side leading to the formation of 2R-hexane-2-ol.
In a SN² reaction since the the nucleophile attacks from the back-side so the product formation takes place with the inversion of configuration.
When the same substrate S-2-iodohexane undergoes a substitution reaction with water as a nucleophile then the reaction occurs through (SN¹) substitution nucleophilic unimolecular mechanism .
The rate of a SN¹ reaction depends only on the nature of substrate and is independent of the nature of nucleophile.
The SN¹ reaction is a 2 step reaction , in the first step leaving group leaves leading to the formation of a carbocation and once the carbocation is formed then any weaker nucleophile or even solvent molecules can attack leading the formation of products.
In this case a secondary carbocation would be generated in the first step and then water will attack this carbocation to form the product in the second step.
The product formed on using water as a nucleophile would be a racemic mixture of R and S isomers of hexane -2-ol in 50:50 ratio. The two products formed would be 2R-hexane-2-ol and 2S-hexane-2-ol.
Kindly refer the attachment for reaction mechanism and structure of products.
Arranged in groups and periods.
Group 1 in the same place.