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FromTheMoon [43]
3 years ago
6

State the definition of the partial molar Gibbs energy.

Chemistry
1 answer:
balu736 [363]3 years ago
4 0

Explanation :

As we know that the Gibbs free energy is not only function of temperature and pressure but also amount of each substance in the system.

G=G(T,P,n_1,n_2)

where,

n_1\text{ and }n_2 is the amount of component 1 and 2 in the system.

Partial molar Gibbs free energy : The partial derivative of Gibbs free energy with respect to amount of component (i) of a mixture when other variable (T,P,n_j) are kept constant are known as partial molar Gibbs free energy of i^{th} component.

For a substance in a mixture, the chemical potential (\mu) is defined as the partial molar Gibbs free energy.

The expression will be:

\bar{G_i}=\mu_i=\frac{\partial G}{\partial n_i}_{(T,P,n_j)}

where,

T = temperature

P = pressure

n_i\text{ and }n_j is the amount of component 'i' and 'j' in the system.

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