Answer:
pH = 1.95
Explanation:
For polyprotic acids, it is generally assumed that all H⁺ comes from the 1st ionization step. The amount of H⁺ delivered into solution for the 2nd and 3rd ionization steps are in the order of 10⁻⁴M and 10⁻⁶M respectively and provide very little change in pH from the quantity delivered in the 1st ionization step.
Therefore... the [H⁺] concentraion and pH are computed as follows...
[H⁺] = √Ka₁[H₃AsO₄] = √(2.5 x 10⁻⁴)(0.500) M = 0.1118M
pH = -log[H⁺] = -log(0.01118) = 1.95
Answer:
![K_2=\frac{[NOBr]^4_{eq}}{[NO]^4_{eq}[Br]^2_{eq}}](https://tex.z-dn.net/?f=K_2%3D%5Cfrac%7B%5BNOBr%5D%5E4_%7Beq%7D%7D%7B%5BNO%5D%5E4_%7Beq%7D%5BBr%5D%5E2_%7Beq%7D%7D)
Explanation:
Hello,
In this case, for the equilibrium condition, the equilibrium constant is defined via the law of mass action, which states that the division between the concentrations of the products over the concentration of the reactants at equilibrium equals the equilibrium constant, for the given reaction:

The suitable equilibrium constant turns out:
![K_2=\frac{[NOBr]^4_{eq}}{[NO]^4_{eq}[Br]^2_{eq}}](https://tex.z-dn.net/?f=K_2%3D%5Cfrac%7B%5BNOBr%5D%5E4_%7Beq%7D%7D%7B%5BNO%5D%5E4_%7Beq%7D%5BBr%5D%5E2_%7Beq%7D%7D)
Or in terms of the initial equilibrium constant:

Since the second reaction is a doubled version of the first one.
Best regards.
Mass of KCl= 1.08 g
<h3>Further explanation</h3>
Given
1 g of K₂CO₃
Required
Mass of KCl
Solution
Reaction
K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂
mol of K₂CO₃(MW=138 g/mol) :
= 1 g : 138 g/mol
= 0.00725
From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :
= 2/1 x mol K₂CO₃
= 2/1 x 0.00725
= 0.0145
Mass of KCl(MW=74.5 g/mol) :
= mol x MW
= 0.0145 x 74.5
= 1.08 g
A vapor is which state of matter?
C. Gas.