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inna [77]
3 years ago
13

The molar enthalpy of vaporization of boron tribromide is 30.5 kj/mol, and its normal boiling point is 91°c. what is the vapor p

ressure of bbr3 at 20°c (r = 8.314j/ k • mol)?
Chemistry
1 answer:
adell [148]3 years ago
5 0
To answer this question, we will use the following equation:
<span>ln(P2/P1) = (∆Hvap/R)*((1/T1) - (1/T2)) 
</span>
Now we examine the givens of the problem and transform to standard units if required:
<span>∆Hvap = 30.5 kJ/mol 
</span>R is a constant = <span>8.314 x 10^-3 kJ K^-1 mol^-1 
T1 </span><span>= 91 celcius = 91 + 273= 364 Kelvin
</span>T2 = 20 celcius = 20 + 273 = 293 k3lvin
P1 is the standard atmospheric pressure = 760 mmHg
P2 is the value to be calculated

Substitute with these values in the equation:
ln(P2/760) = (30.5 / 8.314 x 10^-3) x ((1 / 364) - (1 / 293)) 
ln(P2/760) = - 2.4662 (Take the exponential both sides to eliminate the ln)
P2 / 760 = e^(-2.4462) = 0.0866
P2 = 0.0866 x 760 = 65.816 mmHg
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