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k0ka [10]
3 years ago
11

Cesium-137 is part of the nuclear waste produced by uranium-235 fission. The half-life of cesium-137 is 30.2 years. How much tim

e is required for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value?
Chemistry
1 answer:
Dmitry_Shevchenko [17]3 years ago
8 0

Answer:

There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value

Explanation:

The radioactive decay follows always first-order kinetics where its general law is:

Ln[A] = -Kt + ln[A]₀

<em>Where [A] is actual concentration of the atom, k is rate constant, t is time and [A]₀ is initial concentration.</em>

We can find rate constant from half-life as follows:

<em>Rate constant:</em>

t(1/2) = ln 2 / K

As half-life of Cesium-137 is 30.2 years:

30.2 years = ln 2 / K

<em>K = 0.02295 years⁻¹</em>

Replacing this result and with the given data of the problem:

Ln[A] = -Kt + ln[A]₀

Ln[A] = -0.02295 years⁻¹* t + ln[A]₀

Ln ([A] / [A₀]) = -0.02295 years⁻¹* t

<em>As you want time when [A] is 20% of [A]₀, [A] / [A]₀ = 0.2:</em>

Ln (0.2) = -0.02295 years⁻¹* t

70.1 years = t

<h3>There are required 70.1 years for the activity of a sample of cesium-137 to fall to 20.0 percent of its original value</h3>

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