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galben [10]
3 years ago
7

The molality is temp independent whereas molarity is temperature dependent. Justify.

Chemistry
1 answer:
Elza [17]3 years ago
6 0
Molality is obtained by dividing the number of moles of solute by the mass in kilogram of the solvent. None of the dimensions is dependent in temperature. On the other hand, molarity is obtained by dividing the number of moles of solute by the volume in liters of the solution. Volume is temperature dependent. 
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8 0
2 years ago
At 20°C the vapor pressure of benzene (C6H6) is 75 torr, and that of toluene (C7H8) is 22 torr. Assume that benzene and toluene
valina [46]

Answer: The mole fraction of benzene will be 0.34 and mole fraction of toluene is 0.66

Explanation:

According to Raoult's law, the vapor pressure of a component at a given temperature is equal to the mole fraction of that component multiplied by the vapor pressure of that component in the pure state.

p_1=x_1p_1^0 and p_2=x_2P_2^0

where, x = mole fraction in solution

p^0 = pressure in the pure state

According to Dalton's law, the total pressure is the sum of individual pressures.

p_{total}=p_1+p_2\\p_{total}=x_{benzene}p_{benzene}^0+x_{toluene}P_{toluene}^0

x_{benzene}=x,

x_{toluene}=1-x_{benzene}=1-x,

p_{benzene}^0=75torr

p_{toluene}^0=22torr

p_{total}=40torr

40=x\times 75+(1-x)\times 22

x=0.34

Thus (1-x0 = (1-0.34)=0.66

Thus the mole fraction of benzene will be 0.34 and that of toluene is 0.66

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Answer:

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