Consider the isomerization of butane with equilibrium constant is 2.5 .The system is originally at equilibrium with :
[butane]=1.0 M , [isobutane]=2.5 M
If 0.50 mol/L of butane is added to the original equilibrium mixture and the system shifts to a new equilibrium position, what is the equilibrium concentration of each gas?
Answer:
The equilibrium concentration of each gas:
[Butane] = 1.14 M
[isobutane] = 2.86 M
Explanation:
Butane ⇄ Isobutane
At equilibrium
1.0 M 2.5 M
After addition of 0.50 M of butane:
(1.0 + 0.50) M -
After equilibrium reestablishes:
(1.50-x)M (2.5+x)
The equilibrium expression will wriiten as:
![K_c=\frac{[Isobutane]}{[Butane]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BIsobutane%5D%7D%7B%5BButane%5D%7D)

x = 0.36 M
The equilibrium concentration of each gas:
[Butane]= (1.50-x) = 1.50 M - 0.36M = 1.14 M
[isobutane]= (2.5+x) = 2.50 M + 0.36 M = 2.86 M
Answer:
The approximate bond angle around the central carbon atom in acrolein is 120°.
Explanation:
The structure of acrolein is shown in the attachment. From the structure, we can deduce that the central carbon atom is in an sp2 hybridization (Atoms with a double bond hybridize in an sp2 fashion).
Atoms with sp2 hybridization have trigonal planar geometry, in this kind of hybridization, bonds are oriented the farthest away possible from each other, to minimize overlapping and the angle that allows that is 120°.
1789 -- raité élémentaire de chimie is a textbook written by Antoine Lavoisier published in 1789 and translated into English by Robert Kerr in 1790 under the title Elements of Chemistry