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marissa [1.9K]
3 years ago
13

A sample of gaseous neon atoms at atmospheric pressure and 0 °c contains 2.69 * 1022 atoms per liter. the atomic radius of neon

is 69 pm. what fraction of the space do the atoms occupy? what does this reveal about the separation between atoms in the gaseous phase?
Chemistry
1 answer:
omeli [17]3 years ago
3 0

Explanation

Radius of neon atom : 69 pm = 69\times 10^{-12} m

Volume occupied by the one atom:\frac{4}{3}\pi r^3

=\frac{4}{3}\times 3.14\times(69\times 10^{-12} m)^3=1.37\times 10^{-30} m^3

given that 2.69\times 10^{22} atoms are present in 1L

1 L = 0.001 m^3

The volume occupied by the 2.69\times 10^{22} neon atoms

2.69\times 10^{22}\times 1.37\times 10^{-30} m^3=3.68\times 10^{-8} m^3

Fraction of volume occupied by the neon atom:

=\frac{3.68\times 10^{-8} m^3}{0.001 m^3}=3.68\times 10^{-11} m^3

3.68\times 10^{-11} m^3

The fraction of of volume occupied by the neon atom is very less than the 1 L which indicates the presence of large amount of empty space between the atoms of the gas.

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A solution was prepared by dissolving 0.800 g of sulfur S8, in 100.0 g of acetic acid, HC2H3O2. Calculate the freezing point and
sammy [17]

<u>Answer:</u> The freezing point of solution is 16.5°C and the boiling point of solution is 118.2°C

<u>Explanation:</u>

To calculate the molality of solution, we use the equation:

Molality=\frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ in grams}}

Where,

m_{solute} = Given mass of solute (S_8) = 0.800 g

M_{solute} = Molar mass of solute (S-8) = 256.52 g/mol

W_{solvent} = Mass of solvent (acetic acid) = 100.0 g

Putting values in above equation, we get:

\text{Molality of solution}=\frac{0.800\times 1000}{256.52\times 100.0}\\\\\text{Molality of solution}=0.0312m

  • <u>Calculation for freezing point of solution:</u>

Depression in freezing point is defined as the difference in the freezing point of water and freezing point of solution.

\Delta T_f=\text{freezing point of acetic acid}-\text{Freezing point of solution}

To calculate the depression in freezing point, we use the equation:

\Delta T_f=iK_fm

or,

\text{Freezing point of acetic acid}-\text{Freezing point of solution}=iK_fm

where,

Freezing point of acetic acid = 16.6°C

i = Vant hoff factor = 1 (for non-electrolyte)

K_f = molal freezing point depression constant = 3.59°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

16.6^oC-\text{freezing point of solution}=1\times 3.59^oC/m\times 0.0312m\\\\\text{Freezing point of solution}=16.5^oC

Hence, the freezing point of solution is 16.5°C

  • <u>Calculation for boiling point of solution:</u>

Elevation in boiling point is defined as the difference in the boiling point of solution and freezing point of pure solution.

The equation used to calculate elevation in boiling point follows:

\Delta T_b=\text{Boiling point of solution}-\text{Boiling point of acetic acid}

To calculate the elevation in boiling point, we use the equation:

\Delta T_b=iK_bm

or,

\text{Boiling point of solution}-\text{Boiling point of acetic acid}=iK_fm

where,

Boiling point of acetic acid = 118.1°C

i = Vant hoff factor = 1 (for non-electrolyte)

K_f = molal boiling point elevation constant = 3.08°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

\text{Boiling point of solution}-118.1^oC=1\times 3.08^oC/m\times 0.0312m\\\\\text{Boiling point of solution}=118.2^oC

Hence, the boiling point of solution is 118.2°C

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