Matter with exactly the same __ is a pure substance ?
1 answer:
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Answer:
1) Endothermic.
2)
3)
Explanation:
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1) In this case, for these calorimetry problems, we can realize that since the temperature decreases the reaction is endothermic because it is absorbing heat from the solution, that is why the temperature goes from 22.00 °C to 16.0°C.
2) Now, for the total heat released by the reaction, we first need to assume that all of it is released by the solution since it is possible to assume that the calorimeter is perfectly isolated. In such a way, it is also valid to assume that the specific heat of the solution is 4.184 J/(g°C) as it is mostly water, therefore, the heat released by the reaction is:
3) Finally, since the enthalpy of reaction is calculated by dividing the heat released by the reaction over the moles of the solute, in this case NH4Cl, we proceed as follows:
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Answer:
1.65 L
Explanation:
The equation for the reaction is given as:
A + B ⇄ C
where;
numbers of moles = 0.386 mol C (g)
Volume = 7.29 L
Molar concentration of C =
= 0.053 M
A + B ⇄ C
Initial 0 0 0.530
Change +x +x - x
Equilibrium x x (0.0530 - x)
where
K is given as ; 78.2 atm-1.
So, we have:
Using quadratic formula;
where; a = 78.2 ; b = 1 ; c= - 0.0530
= or
= or
= 0.0204 or -0.0332
Going by the positive value; we have:
x = 0.0204
[A] = 0.0204
[B] = 0.0204
[C] = 0.0530 - x
= 0.0530 - 0.0204
= 0.0326
Total number of moles at equilibrium = 0.0204 + 0.0204 + 0.0326
= 0.0734
Finally, we can calculate the volume of the cylinder at equilibrium using the ideal gas; PV =nRT
if we make V the subject of the formula; we have:
where;
P (pressure) = 1 atm
n (number of moles) = 0.0734 mole
R (rate constant) = 0.0821 L-atm/mol-K
T = 273.15 K (fixed constant temperature )
V (volume) = ???
V = 1.64604
V ≅ 1.65 L