coal gas, gas carbon, coal tar and ammonia liquor,
The second reaction with the volume of 5L will occur faster as compared to the first reaction of volume 10L.
Volume is inversely proportional to the rate of reaction.
As volume increases rate of reaction decreases and as volume decreases rate of reaction increases.
Let's consider a reaction A → B.
r is rate of reaction and K is rate constant, A is the concentration of reaction.
r = k(A)
r is directly proportional to the A.
But the concentration of A is in Moles/liters (i.e. moles per unit volume)
r is inversely proportional to the volume of vessel or chamber.
Hence as volume increases rate of reaction decreases.
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Single replacements since cu is being replaced by zn
Answer:

Explanation:
We are given the volumes and concentrations of two reactants, so this is a limiting reactant problem.
We know that we will need moles, so, lets assemble all the data in one place.
Cu²⁺ + 4NH₃ ⟶ Cu(NH₃)₄²⁺
V/mL: 3.00 7.00
c/mol·L⁻¹: 0.050 0.20
1. Identify the limiting reactant
(a) Calculate the moles of each reactant

(b) Calculate the moles of Cu(NH₃)₄²⁺ that can be formed from each reactant
(i) From Cu²⁺

(ii) From NH₃

NH₃ is the limiting reactant, because it forms fewer moles of the complex ion.
(c) Concentration of the complex ion
