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LenaWriter [7]
3 years ago
11

Consider the following standard reduction potentials in acid solution: The weakest reducing agent listed above is Co Cr Cr3 Mn2

MnO4-
Chemistry
1 answer:
Sliva [168]3 years ago
7 0

This is an complete question, here is a complete question.

Consider the following standard reduction potentials in acid solution:

Cr^{3+}+3e^-\rightarrow Cr      E^o=-0.74V

Co^{2+}+2e^-\rightarrow Co    E^o=-0.28V

MnO_4^-+8H^++5e^-\rightarrow Mn^{2+}+4H_2O    E^o=+1.51V

The weakest reducing agent listed above is:

(a) Cr^{3+}  

(b) Cr  

(c) Mn^{2+}

(d) MnO_4^-

Answer : The correct option is, (d) MnO_4^-

Explanation :

As we know that,

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction and weakest reducing agent or strongest oxidizing agent.

From the standard reduction potentials we conclude that,

MnO_4^- having highest positive E^o potential than the other. So, it will always get reduced and will undergo reduction reaction and weakest reducing agent.

Hence, the correct option is, (d) MnO_4^-

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3 years ago
The equilibrium constant for the reaction AgBr(s) Picture Ag+(aq) + Br− (aq) is the solubility product constant, Ksp = 7.7 × 10−
barxatty [35]

Answer:

The reaction will be  non spontaneous at these concentrations.

Explanation:

AgBr(s)\rightarrow Ag^+(aq) + Br^- (aq)

Expression for an equilibrium constant K_c:

K_c=\frac{[Ag^+][Br^-]}{[AgCl]}=\frac{[Ag^+][Br^-]}{1}=[Ag^+][Br^-]

Solubility product of the reaction:

K_{sp}=[Ag^+][Br^-]=K_c=7.7\times 10^{-13}

Reaction between Gibb's free energy and equilibrium constant if given as:

\Delta G^o=-2.303\times R\times T\times \log K_c

\Delta G^o=-2.303\times R\times T\times \log K_{sp}

\Delta G^o=-2.303\times 8.314 J/K mol\times 298 K\times \log[7.7\times 10^{-13}]

\Delta G^o=69,117.84 J/mol=69.117 kJ/mol

Gibb's free energy when concentration [Ag^+] = 1.0\times 10^{-2} M and [Br^-] = 1.0\times 10^{-3} M

Reaction quotient of an equilibrium = Q

Q=[Ag^+][Br^-]=1.0\times 10^{-2} M\times 1.0\times 10^{-3} M=1.0\times 10^{-5}

\Delta G=\Delta G^o+(2.303\times R\times T\times \log Q)

\Delta G=69.117 kJ/mol+(2.303\times 8.314 Joule/mol K\times 298 K\times \log[1.0\times 10^{-5}])

\Delta G=40.588 kJ/mol

  • For reaction to spontaneous reaction:  \Delta G.
  • For reaction to non spontaneous reaction:  \Delta G>0.

Since ,the value of Gibbs free energy is greater than zero which means reaction will be non spontaneous at these concentrations

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