In liquids, particles are slightly spaced from each other and move around somewhat freely, but still bump into each other. Gases on the other hand move randomly and rarely bump into each other, thus they are more spaced out.
The study of metals and the process for refining and making things from them is called metallurgy.
Metallurgy is said to be the scientific study both of the extraction and refining process of metals from their ores.
This process includes steps such as grinding of the ore also called ore pulverization.
Ore is crushed to increase its surface area for purpose of increasing the level of its reactivity.
Sometimes, the ore is heated in the presence of oxygen to turn the ore into and oxide. This process is known as roasting.
Answer:
The position of an equilibrium always shifts in such a direction as to relieve a stress applied to the system. - <u>Le Chatelier's principle</u>
A molecule that donates a proton when it encounters a proton acceptor. - <u>Bronsted-Lowry acid</u>
Occurs when a reaction involving an acid and its conjugate base is combined with a second reaction involving a base and its conjugate acid. - <u>Neutralization</u>
It ionizes completely when dissolved in water. - <u>Strong acid</u>
The shift in the position of equilibrium caused by the addition of a participating ion. - <u>Common ion effect</u>
It only partially ionizes when dissolved in water. - <u>Weak electrolyte</u>
It is capable of acting as either an acid or a base depending upon the solute. - <u>Amphoteric solvent</u>
The act of self-ionization of a solvent to produce both a conjugate acid and a conjugate base. - <u>autoprotolysis </u>
A chemical species that bears both positive and negative charges. - <u>zwitter ion</u>
Answer:
Explanation:
From the given information:
A → B k₁
B → A k₂
B + C → D k₃
The rate law = ![\dfrac{d[D]}{dt}=k_3[B][C] --- (1)](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%3Dk_3%5BB%5D%5BC%5D%20---%20%281%29)
![\dfrac{d[B]}{dt}=k[A] -k_2[B] -k_3[B][C]](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BB%5D%7D%7Bdt%7D%3Dk%5BA%5D%20-k_2%5BB%5D%20-k_3%5BB%5D%5BC%5D)
Using steady-state approximation;
![\dfrac{d[B]}{dt}=0](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BB%5D%7D%7Bdt%7D%3D0)
![k_1[A]-k_2[B]-k_3[B][C] = 0](https://tex.z-dn.net/?f=k_1%5BA%5D-k_2%5BB%5D-k_3%5BB%5D%5BC%5D%20%3D%200)
![[B] = \dfrac{k_1[A]}{k_2+k_3[C]}](https://tex.z-dn.net/?f=%5BB%5D%20%3D%20%5Cdfrac%7Bk_1%5BA%5D%7D%7Bk_2%2Bk_3%5BC%5D%7D)
From equation (1), we have:
![\mathbf{\dfrac{d[D]}{dt}= \dfrac{k_3k_1[A][C]}{k_2+k_3[C]}}](https://tex.z-dn.net/?f=%5Cmathbf%7B%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_2%2Bk_3%5BC%5D%7D%7D)
when the pressure is high;
k₂ << k₃[C]
![\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_3[C]}= k_1A \ \ \text{first order}](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%20%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_3%5BC%5D%7D%3D%20k_1A%20%5C%20%5C%20%20%5Ctext%7Bfirst%20order%7D)
k₂ >> k₃[C]
![\dfrac{d[D]}{dt} = \dfrac{k_3k_1[A][C]}{k_2}= \dfrac{k_1k_3}{k_2}[A][C] \ \ \text{second order}](https://tex.z-dn.net/?f=%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D%20%3D%20%5Cdfrac%7Bk_3k_1%5BA%5D%5BC%5D%7D%7Bk_2%7D%3D%20%5Cdfrac%7Bk_1k_3%7D%7Bk_2%7D%5BA%5D%5BC%5D%20%5C%20%5C%20%20%5Ctext%7Bsecond%20order%7D)