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Pepsi [2]
3 years ago
8

Consider the following mechanism.

Chemistry
1 answer:
solong [7]3 years ago
7 0

Answer :

(a) The overall equation is:

ClO^-(aq)+I^-(aq)\rightarrow Cl^-(aq)+IO^-(aq)

(b) The intermediates are  :

OH^-(aq),HClO(aq)\text{ and }HIO(aq)

Explanation :

<u>Part (a) :</u>

(1) ClO^-(aq)+H_2O(l)\rightarrow HClO(aq)+OH^-(aq)   (fast)

(2) I^-(aq)+HClO(aq)\rightarrow HIO(aq)+Cl^-(aq)    (slow)

(3) OH^-(aq)+HIO(aq)\rightarrow H_2O(l)+IO^-(aq)   (fast)

By adding the three equations and cancelling the common terms on both side, we will get the overall equation.

ClO^-(aq)+I^-(aq)\rightarrow Cl^-(aq)+IO^-(aq)

<u>Part (b)  :</u>

Intermediates are generated and consumed in the mechanism and do not include in the overall equation.

Since, intermediates will not include in the overall mechanism.

The intermediates are  :

OH^-(aq),HClO(aq)\text{ and }HIO(aq)

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Read 2 more answers
8) Determine whether mixing each pair of the following results in a buffera. 100.0 mL of 0.10 M NH3 with 100.0 mL of 0.15 MNH4Cl
Marina86 [1]

Answer:

a. 100.0 mL of 0.10 M NH₃ with 100.0 mL of 0.15 M NH₄Cl.

c. 50.0 mL of 0.15 M HF with 20.0 mL of 0.15 M NaOH.

Explanation:

A buffer system is formed in 1 of 2 ways:

  • A weak acid and its conjugate base.
  • A weak base and its conjugate acid.

Determine whether mixing each pair of the following results in a buffer.

a. 100.0 mL of 0.10 M NH₃ with 100.0 mL of 0.15 M NH₄Cl.

YES. NH₃ is a weak base and NH₄⁺ (from NH₄Cl ) is its conjugate base.

b. 50.0 mL of 0.10 M HCl with 35.0 mL of 0.150 M NaOH.

NO. HCl is a strong acid and NaOH is a strong base.

c. 50.0 mL of 0.15 M HF with 20.0 mL of 0.15 M NaOH.

YES. HF is a weak acid and it reacts with NaOH to form NaF, which contains F⁻ (its conjugate base).

d. 175.0 mL of 0.10 M NH₃ with 150.0 mL of 0.12 M NaOH.

NO. Both are bases.

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